| Literature DB >> 20567786 |
Hisashi Umemoto1, Kazunori Ohashi, Takashi Inoue, Nobuyuki Fukui, Toshiki Sugai, Hisanori Shinohara.
Abstract
The first T(d)-symmetric lutetium metallofullerene, Lu(2)@C(76), has been synthesized, isolated, and characterized. Because of the charge transfer from the encapsulated Lu atoms to the T(d)-C(76) fullerene cage, the otherwise unstable T(d)-C(76) fullerene can be significantly stabilized as a Lu(2)@C(76) fullerene. Both STM and STS results are consistent with a charge state of (Lu(2))(6+)@C(76)(6-)(T(d)).Entities:
Year: 2010 PMID： 20567786 DOI： 10.1039/c0cc00824a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222