Literature DB >> 20544123

Method for regio-, chemo- and stereoselective deuterium labeling of sugars based on ruthenium-catalyzed C-H bond activation.

Yuta Fujiwara1, Hiroki Iwata, Yoshinari Sawama, Yasunari Monguchi, Hironao Sajiki.   

Abstract

An efficient and facile deuterium labeling of sugars has been achieved in a completely regio-, chemo- and stereoselective manner using the Ru/C-H(2)-D(2)O combination via C-H bond activation assisted by the coordination of Ru to the oxygen atom of the sugar-hydroxyl groups.

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Year:  2010        PMID： 20544123     DOI： 10.1039/c0cc01197e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Perdeuterated and 13C-enriched myo-inositol for DNP assisted monitoring of enzymatic phosphorylation by inositol-3-kinase.

Authors:  M J Moure; Y Zhuo; G J Boons; J H Prestegard
Journal:  Chem Commun (Camb)       Date:  2017-11-16       Impact factor: 6.222

2.  Practical Synthesis of C-1 Deuterated Aldehydes Enabled by NHC Catalysis.

Authors:  Huihui Geng; Xiaobei Chen; Jingjing Gui; Yueteng Zhang; Zuyuan Shen; Pengfei Qian; Junwei Chen; Shilei Zhang; Wei Wang
Journal:  Nat Catal       Date:  2019-10-28

3.  Iridium-catalyzed α-selective deuteration of alcohols.

Authors:  Moeko Itoga; Masako Yamanishi; Taro Udagawa; Ayane Kobayashi; Keiko Maekawa; Yoshiji Takemoto; Hiroshi Naka
Journal:  Chem Sci       Date:  2022-07-06       Impact factor: 9.969

4.  Heavy water recycling for producing deuterium compounds.

Authors:  Kazuhiro Akutsu-Suyama; Hironao Sajiki; Misaki Ueda; Makiko Asamoto; Yasuyuki Tsutsumi
Journal:  RSC Adv       Date:  2022-08-31       Impact factor: 4.036

5.  Measuring glucose cerebral metabolism in the healthy mouse using hyperpolarized 13C magnetic resonance.

Authors:  Mor Mishkovsky; Brian Anderson; Magnus Karlsson; Mathilde H Lerche; A Dean Sherry; Rolf Gruetter; Zoltan Kovacs; Arnaud Comment
Journal:  Sci Rep       Date:  2017-09-15       Impact factor: 4.379
  5 in total

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