| Literature DB >> 20540522 |
Ine I F Boogaerts1, Steven P Nolan.
Abstract
A highly efficient [(NHC)Au(I)]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.Entities:
Year: 2010 PMID： 20540522 DOI： 10.1021/ja103429q
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419