Literature DB >> 20480095

Ammonia N-H activation by a N,N'-diamidocarbene.

Todd W Hudnall1, Jonathan P Moerdyk, Christopher W Bielawski.   

Abstract

The synthesis and characterization of N,N'-dimesityl-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene is reported; this crystalline N,N'-diamidocarbene was found to split ammonia and engage in other reactions not exhibited by typical N-heterocyclic carbenes.

Entities:  

Year:  2010        PMID： 20480095     DOI： 10.1039/c0cc00638f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

1.  Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents.

Authors:  Jonathan P Moerdyk; Christopher W Bielawski
Journal:  Nat Chem       Date:  2012-02-12       Impact factor: 24.427

2.  Stable singlet carbenes as mimics for transition metal centers.

Authors:  David Martin; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Sci       Date:  2011-01-01       Impact factor: 9.825

3.  A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand.

Authors:  David Martin; Vanessa M Marx; Robert H Grubbs; Guy Bertrand
Journal:  Adv Synth Catal       Date:  2016-02-09       Impact factor: 5.837

4.  Preparation and use of carbonyl-decorated carbenes in the activation of white phosphorus.

Authors:  Antonio J Torres; Christopher L Dorsey; Todd W Hudnall
Journal:  J Vis Exp       Date:  2014-10-03       Impact factor: 1.355

5.  Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors:  Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Sci       Date:  2013-08-01       Impact factor: 9.825

6.  A comparison of diamino- and diamidocarbenes toward dimerization.

Authors:  Chin-Hung Lai
Journal:  J Mol Model       Date:  2013-08-06       Impact factor: 1.810

7.  Computational comparison of the kinetic stabilities of diamino- and diamidocarbenes in the 1,2-H shift reaction.

Authors:  Chin-Hung Lai
Journal:  J Mol Model       Date:  2013-04-05       Impact factor: 1.810

8.  A theoretical study on the hydrogen adducts of diamidocarbenes and diaminocarbenes.

Authors:  Chin Hung Lai
Journal:  J Mol Model       Date:  2013-11-19       Impact factor: 1.810

9.  Reaction Mechanism of Li and Mg Carbenoid Cyclopropanations: Metal-π and σ Interactions.

Authors:  Daniel Villablanca; Rocio Durán; Al Mokhtar Lamsabhi; Barbara Herrera
Journal:  ACS Omega       Date:  2019-11-08

10.  Copper diamidocarbene complexes: characterization of monomeric to tetrameric species.

Authors:  Lee R Collins; John P Lowe; Mary F Mahon; Rebecca C Poulten; Michael K Whittlesey
Journal:  Inorg Chem       Date:  2014-02-11       Impact factor: 5.165
  10 in total

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