Literature DB >> 21743834

Stable singlet carbenes as mimics for transition metal centers.

David Martin1, Michele Soleilhavoup, Guy Bertrand.   

Abstract

This perspective summarizes recent results, which demonstrate that stable class="Chemical">carbenes can activate small molecules (<class="Chemical">span class="Chemical">CO, H(2), NH(3) and P(4)) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive for transition metal complexes.

Entities:  

Year:  2011        PMID： 21743834      PMCID： PMC3129870          DOI： 10.1039/C0SC00388C

Source DB:  PubMed          Journal:  Chem Sci        ISSN： 2041-6520            Impact factor:   9.825


  111 in total

1.  CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

Authors:  Vincent Lavallo; Yves Canac; Bruno Donnadieu; Wolfgang W Schoeller; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2006-05-19       Impact factor: 15.336

2.  [[HC(CMeNAr)(2)](2)Al(2)P(4)] (Ar=2,6-iPr(2)C(6)H(3)): a reduction to a formal [P(4)](4-) charged species.

Authors:  Ying Peng; Hongjun Fan; Hongping Zhu; Herbert W Roesky; Jörg Magull; Colan E Hughes
Journal:  Angew Chem Int Ed Engl       Date:  2004-06-28       Impact factor: 15.336

3.  Carbene activation of P4 and subsequent derivatization.

Authors:  Jason D Masuda; Wolfgang W Schoeller; Bruno Donnadieu; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

4.  A stable chiral diaminocyclopropenylidene.

Authors:  Dirk Holschumacher; Cristian G Hrib; Peter G Jones; Matthias Tamm
Journal:  Chem Commun (Camb)       Date:  2007-06-25       Impact factor: 6.222

5.  Carbene stabilization of diarsenic: from hypervalency to allotropy.

Authors:  Mariham Y Abraham; Yuzhong Wang; Yaoming Xie; Pingrong Wei; Henry F Schaefer; P von R Schleyer; Gregory H Robinson
Journal:  Chemistry       Date:  2010-01-11       Impact factor: 5.236

6.  Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications.

Authors:  Olivier Back; Bruno Donnadieu; Pattiyil Parameswaran; Gernot Frenking; Guy Bertrand
Journal:  Nat Chem       Date:  2010-04-11       Impact factor: 24.427

7.  Oxidative addition of ammonia at a silicon(II) center and an unprecedented hydrogenation reaction of compounds with low-valent group 14 elements using ammonia borane.

Authors:  Anukul Jana; Carola Schulzke; Herbert W Roesky
Journal:  J Am Chem Soc       Date:  2009-04-08       Impact factor: 15.419

8.  N-heterocyclic carbene boryl radicals: a new class of boron-centered radical.

Authors:  Shau-Hua Ueng; Andrey Solovyev; Xinting Yuan; Steven J Geib; Louis Fensterbank; Emmanuel Lacôte; Max Malacria; Martin Newcomb; John C Walton; Dennis P Curran
Journal:  J Am Chem Soc       Date:  2009-08-12       Impact factor: 15.419

9.  Cleavage of a N-H bond of ammonia at room temperature by a germylene.

Authors:  Anukul Jana; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Journal:  Inorg Chem       Date:  2009-02-02       Impact factor: 5.165

10.  Diarylstannylene activation of hydrogen or ammonia with arene elimination.

Authors:  Yang Peng; Bobby D Ellis; Xinping Wang; Philip P Power
Journal:  J Am Chem Soc       Date:  2008-08-21       Impact factor: 15.419
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  31 in total

1.  Main group chemistry: Bonsai phosphorus.

Authors:  Emma E Coyle; Christopher J O'Brien
Journal:  Nat Chem       Date:  2012-10       Impact factor: 24.427

2.  Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents.

Authors:  Jonathan P Moerdyk; Christopher W Bielawski
Journal:  Nat Chem       Date:  2012-02-12       Impact factor: 24.427

3.  A Brief Survey of our Contribution to Stable Carbene Chemistry.

Authors:  David Martin; Mohand Melaimi; Michele Soleilhavoup; Guy Bertrand
Journal:  Organometallics       Date:  2011-09-22       Impact factor: 3.876

4.  A silicon-carbonyl complex stable at room temperature.

Authors:  Chelladurai Ganesamoorthy; Juliane Schoening; Christoph Wölper; Lijuan Song; Peter R Schreiner; Stephan Schulz
Journal:  Nat Chem       Date:  2020-04-20       Impact factor: 24.427

5.  Multiple complexation of CO and related ligands to a main-group element.

Authors:  Holger Braunschweig; Rian D Dewhurst; Florian Hupp; Marco Nutz; Krzysztof Radacki; Christopher W Tate; Alfredo Vargas; Qing Ye
Journal:  Nature       Date:  2015-06-18       Impact factor: 49.962

Review 6.  Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.

Authors:  Saroj Kumar Kushvaha; Ankush Mishra; Herbert W Roesky; Kartik Chandra Mondal
Journal:  Chem Asian J       Date:  2022-02-26

7.  An overview of N-heterocyclic carbenes.

Authors:  Matthew N Hopkinson; Christian Richter; Michael Schedler; Frank Glorius
Journal:  Nature       Date:  2014-06-26       Impact factor: 49.962

8.  Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors:  Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Sci       Date:  2013-08-01       Impact factor: 9.825

9.  Changes in ligating abilities of the singlet and triplet states of normal, abnormal and remote N-heterocyclic carbenes depending on their aromaticities.

Authors:  Resul Sevinçek; Hande Karabıyık; Hasan Karabıyık
Journal:  J Mol Model       Date:  2013-10-25       Impact factor: 1.810

10.  Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene.

Authors:  Zhaowen Dong; Jan Mathis Winkler; Marc Schmidtmann; Thomas Müller
Journal:  Chem Sci       Date:  2021-03-22       Impact factor: 9.825
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