Literature DB >> 20431010

Conversion of sugars to lactic acid derivatives using heterogeneous zeotype catalysts.

Martin Spangsberg Holm1, Shunmugavel Saravanamurugan, Esben Taarning.   

Abstract

Presently, very few compounds of commercial interest are directly accessible from carbohydrates by using nonfermentive approaches. We describe here a catalytic process for the direct formation of methyl lactate from common sugars. Lewis acidic zeotypes, such as Sn-Beta, catalyze the conversion of mono- and disaccharides that are dissolved in methanol to methyl lactate at 160 degrees C. With sucrose as the substrate, methyl lactate yield reaches 68%, and the heterogeneous catalyst can be easily recovered by filtration and reused multiple times after calcination without any substantial change in the product selectivity.

Entities:  

Year:  2010        PMID: 20431010     DOI: 10.1126/science.1183990

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  31 in total

1.  Metalloenzyme-like catalyzed isomerizations of sugars by Lewis acid zeolites.

Authors:  Ricardo Bermejo-Deval; Rajeev S Assary; Eranda Nikolla; Manuel Moliner; Yuriy Román-Leshkov; Son-Jong Hwang; Arna Palsdottir; Dorothy Silverman; Raul F Lobo; Larry A Curtiss; Mark E Davis
Journal:  Proc Natl Acad Sci U S A       Date:  2012-06-04       Impact factor: 11.205

2.  Solvent-Activated Hafnium-Containing Zeolites Enable Selective and Continuous Glucose-Fructose Isomerisation.

Authors:  Luca Botti; Simon A Kondrat; Ricardo Navar; Daniele Padovan; Juan S Martinez-Espin; Sebastian Meier; Ceri Hammond
Journal:  Angew Chem Int Ed Engl       Date:  2020-08-31       Impact factor: 15.336

3.  Tandem catalysis for the production of alkyl lactates from ketohexoses at moderate temperatures.

Authors:  Marat Orazov; Mark E Davis
Journal:  Proc Natl Acad Sci U S A       Date:  2015-09-08       Impact factor: 11.205

4.  Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites with 15N Pyridine Adsorption Coupled with MAS NMR Spectroscopy.

Authors:  William R Gunther; Vladimir K Michaelis; Robert G Griffin; Yuriy Román-Leshkov
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2016-09-21       Impact factor: 4.126

5.  High-Productivity Continuous Conversion of Glucose to α-Hydroxy Esters over Postsynthetic and Hydrothermal Sn-Beta Catalysts.

Authors:  Luca Botti; Ricardo Navar; Søren Tolborg; Juan S Martínez-Espín; Ceri Hammond
Journal:  ACS Sustain Chem Eng       Date:  2022-03-30       Impact factor: 8.198

6.  Efficient Conversion of Glucose to Methyl Lactate with Sn-USY: Retro-aldol Activity Promotion by Controlled Ion Exchange.

Authors:  Jose M Jimenez-Martin; Ana Orozco-Saumell; Héctor Hernando; María Linares; Rafael Mariscal; Manuel López Granados; Alicia García; Jose Iglesias
Journal:  ACS Sustain Chem Eng       Date:  2022-06-28       Impact factor: 9.224

7.  Deprotonation and acidity characterization of biomass sugars: a first-principles study.

Authors:  Gang Yang; Chang Zhu; Lijun Zhou
Journal:  J Mol Model       Date:  2016-04-13       Impact factor: 1.810

8.  A bio-catalytic approach to aliphatic ketones.

Authors:  Mingyong Xiong; Jin Deng; Adam P Woodruff; Minshan Zhu; Jun Zhou; Sun Wook Park; Hui Li; Yao Fu; Kechun Zhang
Journal:  Sci Rep       Date:  2012-03-13       Impact factor: 4.379

9.  Sn-Beta zeolites with borate salts catalyse the epimerization of carbohydrates via an intramolecular carbon shift.

Authors:  William R Gunther; Yuran Wang; Yuewei Ji; Vladimir K Michaelis; Sean T Hunt; Robert G Griffin; Yuriy Román-Leshkov
Journal:  Nat Commun       Date:  2012       Impact factor: 14.919

10.  Identification of Active and Spectator Sn Sites in Sn-β Following Solid-State Stannation, and Consequences for Lewis Acid Catalysis.

Authors:  Ceri Hammond; Daniele Padovan; Abbas Al-Nayili; Peter P Wells; Emma K Gibson; Nikolaos Dimitratos
Journal:  ChemCatChem       Date:  2015-09-01       Impact factor: 5.686

View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.