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Literature DB >> 20225875

Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes.

Xingang Zhang¹, Shilu Fan, Chun-Yang He, Xiaolong Wan, Qiao-Qiao Min, Jie Yang, Zhong-Xing Jiang.

Abstract

An efficient, Pd(OAc)(2) catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.

Entities: Chemical

Mesh：

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Year: 2010 PMID： 20225875 DOI： 10.1021/ja908434e

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

7 in total

1. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

Authors: Jian He; Ryosuke Takise; Haiyan Fu; Jin-Quan Yu
Journal: J Am Chem Soc Date: 2015-04-02 Impact factor: 15.419

2. Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically nonbiased olefins.

Authors: Erik W Werner; Matthew S Sigman
Journal: J Am Chem Soc Date: 2011-06-06 Impact factor: 15.419

3. A highly selective and general palladium catalyst for the oxidative Heck reaction of electronically nonbiased olefins.

Authors: Erik W Werner; Matthew S Sigman
Journal: J Am Chem Soc Date: 2010-10-13 Impact factor: 15.419

7. Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp(2))-H bond arylations.

Authors: Fatiha Abdelmalek; Fazia Derridj; Safia Djebbar; Jean-François Soulé; Henri Doucet
Journal: Beilstein J Org Chem Date: 2015-10-28 Impact factor: 2.883

7 in total

Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes.

1. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

2. Operationally simple and highly (E)-styrenyl-selective Heck reactions of electronically nonbiased olefins.

3. A highly selective and general palladium catalyst for the oxidative Heck reaction of electronically nonbiased olefins.

4. N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones.

5. Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.

6. Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.

7. Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp(2))-H bond arylations.