Literature DB >> 20170088

Fluorous mixture synthesis of asymmetric dendrimers.

Zhong-Xing Jiang1, Yihua Bruce Yu.   

Abstract

A divergent fluorous mixture synthesis (FMS) of asymmetric fluorinated dendrimers has been developed. Four generations of fluorinated dendrimers with the same fluorinated moiety were prepared with high efficiency, yield, and purity. Comparison of the physicochemical properties of these dendrimers provided valuable information for their application and future optimization. This strategy has not only provided a practical method for the synthesis and purification of dendrimers, but also established the possibility of utilizing the same fluorinated moiety for FMS.

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Year:  2010        PMID： 20170088      PMCID： PMC2882623          DOI： 10.1021/jo100102a

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  18 in total

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  5 in total

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2.  The Effect of Column and Eluent Fluorination on the Retention and Separation of non-Fluorinated Amino Acids and Proteins by HPLC.

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Journal:  J Fluor Chem       Date:  2011-02-01       Impact factor: 2.050

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5.  Conformational transition of a non-associative fluorinated amphiphile in aqueous solution. II. Conformational transition vs. supramolecular assembly.

Authors:  Marc B Taraban; Daniel J Deredge; Margaret E Smith; Katharine T Briggs; Yue Feng; Yu Li; Zhong-Xing Jiang; Patrick L Wintrode; Yihua Bruce Yu
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  5 in total

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