Literature DB >> 20162188

Heterotrimetallic 3d-4d-4f decanuclear metal-capped square showing single-molecule magnet behavior.

Jérôme Long1, Lise-Marie Chamoreau, Valérie Marvaud.   

Abstract

The synthesis, the structural characterization and the magnetic properties of a heterotrimetallic decanuclear square, [(Mo(CN)(8))(2)(CuLTb)(4))](4+), noted MoCuTb, are described. This supramolecular compound, viewed as the first example of a metal-capped square, behaves as a single molecule magnet with a magnetic anisotropic barrier energy of U(eff) = 13.40 cm(-1) (19.25 K).

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Year:  2010        PMID： 20162188     DOI： 10.1039/b924644b

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Syntheses, crystal structures, magnetic properties and ESI-MS studies of a series of trinuclear CuIIMIICuII compounds (M = Cu, Ni, Co, Fe, Mn, Zn).

Authors:  Nairita Hari; Shuvankar Mandal; Arpita Jana; Hazel A Sparkes; Sasankasekhar Mohanta
Journal:  RSC Adv       Date:  2018-02-14       Impact factor: 4.036

2.  Crystal structure of aqua-1κO-{μ-2-[(2-hydroxy-ethyl)methylamino]ethanolato-2:1κ(4) O (1),N,O (2):O (1)}[μ-2,2'-(methylimino)diethanolato-1:2κ(4) O,N,O':O]dithiocyanato-1κN,2κN-chromium(III)copper(II).

Authors:  Julia A Rusanova; Valentina V Semenaka; Viktoriya V Dyakonenko; Oleg V Shishkin
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-08-26

3.  Bis(μ-6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolato)nickel(II) methanol monosolvate.

Authors:  Fan-Kun Meng; Xin Zhang; Hua Yi; De-Hui Zhang; Jun-Ying Jia
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-06-29
  3 in total

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