Literature DB >> 20104844

Zinc-catalyzed reduction of amides: unprecedented selectivity and functional group tolerance.

Shoubhik Das1, Daniele Addis, Shaolin Zhou, Kathrin Junge, Matthias Beller.   

Abstract

A novel zinc-catalyzed reduction of tertiary amides was developed. This system shows remarkable chemoselectivity and substrate scope tolerating ester, ether, nitro, cyano, azo, and keto substituents.

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Year:  2010        PMID： 20104844     DOI： 10.1021/ja910083q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

1.  Nickel-Catalyzed Reduction of Secondary and Tertiary Amides.

Authors:  Bryan J Simmons; Marie Hoffmann; Jaeyeon Hwang; Moritz K Jackl; Neil K Garg
Journal:  Org Lett       Date:  2017-03-24       Impact factor: 6.005

2.  Highly functionalized donor-acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids.

Authors:  Alexander F G Goldberg; Robert A Craig; Nicholas R O'Connor; Brian M Stoltz
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

Review 3.  s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors:  Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal:  Chem Rev       Date:  2022-03-07       Impact factor: 72.087

4.  Reduction of liquid terminated-carboxyl fluoroelastomers using NaBH4/SmCl3.

Authors:  Yunfei Chang; Mingyi Liao; Xueyan Li
Journal:  RSC Adv       Date:  2020-03-17       Impact factor: 3.361

5.  Iridium-catalyzed reductive nitro-Mannich cyclization.

Authors:  Alex W Gregory; Alan Chambers; Alison Hawkins; Pavol Jakubec; Darren J Dixon
Journal:  Chemistry       Date:  2014-11-14       Impact factor: 5.236

6.  Multicomponent reaction-based synthesis and biological evaluation of tricyclic heterofused quinolines with multi-trypanosomatid activity.

Authors:  Ornella Di Pietro; Esther Vicente-García; Martin C Taylor; Diana Berenguer; Elisabet Viayna; Anna Lanzoni; Irene Sola; Helena Sayago; Cristina Riera; Roser Fisa; M Victòria Clos; Belén Pérez; John M Kelly; Rodolfo Lavilla; Diego Muñoz-Torrero
Journal:  Eur J Med Chem       Date:  2015-10-19       Impact factor: 6.514

7.  Tertiary amine synthesis via reductive coupling of amides with Grignard reagents.

Authors:  Lan-Gui Xie; Darren J Dixon
Journal:  Chem Sci       Date:  2017-09-11       Impact factor: 9.825

8.  Mimicking transition metals in borrowing hydrogen from alcohols.

Authors:  Ananya Banik; Jasimuddin Ahmed; Swagata Sil; Swadhin K Mandal
Journal:  Chem Sci       Date:  2021-05-07       Impact factor: 9.825

9.  Highly chemoselective reduction of amides (primary, secondary, tertiary) to alcohols using SmI2/amine/H2O under mild conditions.

Authors:  Michal Szostak; Malcolm Spain; Andrew J Eberhart; David J Procter
Journal:  J Am Chem Soc       Date:  2014-01-31       Impact factor: 15.419

10.  Platinum-Catalyzed Reduction of DMF by 1,1,3,3-Tetramethyldisiloxane, HMeSi2OSiMe2H: New Intermediates HSiMe2OSiMe2OCH2NMe2 and HSiMe2(OSiMe2)3OCH2NMe2 and Their Further Chemical Reactivity.

Authors:  Jorge L Martinez; Hemant K Sharma; Renzo Arias-Ugarte; Keith H Pannell
Journal:  Organometallics       Date:  2014-06-11       Impact factor: 3.876
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