| Literature DB >> 19907778 |
Roman Maag1, Brian H Northrop, Anna Butterfield, Anthony Linden, Oliver Zerbe, Young Min Lee, Ki-Whan Chi, Peter J Stang, Jay S Siegel.
Abstract
The synthesis and characterization of two direct platinum (1 and 6a/b) and three ethynyl-platinum corannulene derivatives (2, 8 and 9), bearing 2, 4, or 5 square planar platinum centers, are presented. The structure of the bowl bearing substituents remains comparable to corannulene and the dynamic behavior of the bowl inversion as assessed by VT NMR supports a persistent bowl structure in solution. These platinum-corannulenes are well-structured tectons for the future assembly of coordination Platonic polyhedra.Entities:
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Year: 2009 PMID: 19907778 PMCID: PMC2805086 DOI: 10.1039/b916020e
Source DB: PubMed Journal: Org Biomol Chem ISSN: 1477-0520 Impact factor: 3.876