Literature DB >> 19623591

Hypervalent carbon atom: "freezing" the S(N)2 transition state.

Simon C A H Pierrefixe1, Sebastiaan J M van Stralen, Joost N P van Stralen, Célia Fonseca Guerra, F Matthias Bickelhaupt.   

Abstract

Entities:  

Year:  2009        PMID： 19623591     DOI： 10.1002/anie.200902125

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


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  6 in total

1.  The rational design of helium bonds.

Authors:  Henry S Rzepa
Journal:  Nat Chem       Date:  2010-03-28       Impact factor: 24.427

2.  Eight-coordinate fluoride in a silicate double-four-ring.

Authors:  Maarten G Goesten; Roald Hoffmann; F Matthias Bickelhaupt; Emiel J M Hensen
Journal:  Proc Natl Acad Sci U S A       Date:  2017-01-17       Impact factor: 11.205

3.  Activation Strain Analysis of SN2 Reactions at C, N, O, and F Centers.

Authors:  Jan Kubelka; F Matthias Bickelhaupt
Journal:  J Phys Chem A       Date:  2017-01-20       Impact factor: 2.781

4.  Flat corannulene: when a transition state becomes a stable molecule.

Authors:  Ephrath Solel; Doron Pappo; Ofer Reany; Tom Mejuch; Renana Gershoni-Poranne; Mark Botoshansky; Amnon Stanger; Ehud Keinan
Journal:  Chem Sci       Date:  2020-10-22       Impact factor: 9.825

Review 5.  Nucleophilic Substitution (SN 2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent.

Authors:  Trevor A Hamlin; Marcel Swart; F Matthias Bickelhaupt
Journal:  Chemphyschem       Date:  2018-04-19       Impact factor: 3.102

6.  A Unified Framework for Understanding Nucleophilicity and Protophilicity in the SN 2/E2 Competition.

Authors:  Pascal Vermeeren; Thomas Hansen; Paul Jansen; Marcel Swart; Trevor A Hamlin; F Matthias Bickelhaupt
Journal:  Chemistry       Date:  2020-10-22       Impact factor: 5.236
  6 in total

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