Literature DB >> 19397326

A chiral 60-metal sodalite cage featuring 24 vertex-sharing [Er4(mu3-OH)4] cubanes.

Xiang-Jian Kong1, Yinglan Wu, La-Sheng Long, Lan-Sun Zheng, Zhiping Zheng.   

Abstract

A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported. The cluster core possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er(4)(mu(3)-OH)(4)](8+) units. The hexagonal face of the sodalite cage features a templating mu(6)-CO(3)(2-) ion. Magnetic studies revealed weak antiferromagnetic interactions.

Entities:  

Year:  2009        PMID： 19397326     DOI： 10.1021/ja901214d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Development of composite inorganic building blocks for MOFs.

Authors:  Shou-Tian Zheng; Tao Wu; Chengtsung Chou; Addis Fuhr; Pingyun Feng; Xianhui Bu
Journal:  J Am Chem Soc       Date:  2012-02-27       Impact factor: 15.419

2.  Cation-mediated optical resolution and anticancer activity of chiral polyoxometalates built from entirely achiral building blocks.

Authors:  Zhi-Ming Zhang; Xiaopin Duan; Shuang Yao; Zhishu Wang; Zekai Lin; Yang-Guang Li; La-Sheng Long; En-Bo Wang; Wenbin Lin
Journal:  Chem Sci       Date:  2016-03-09       Impact factor: 9.825

3.  Sorting Phenomena and Chirality Transfer in Fluoride-Bridged Macrocyclic Rare Earth Complexes.

Authors:  Katarzyna Ślepokura; Trevor A Cabreros; Gilles Muller; Jerzy Lisowski
Journal:  Inorg Chem       Date:  2021-11-16       Impact factor: 5.165

4.  Rare Silver-Histidine Cluster Complex and Its Single-Crystal-to-Single-Crystal Phase-Transition Behavior.

Authors:  Qingxin Liu; Yinglan Wu; Min Feng; Wanmin Chen; Zhiping Zheng
Journal:  ACS Omega       Date:  2022-02-23
  4 in total

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