Literature DB >> 19377689

An efficient aerobic oxidative cyanation of tertiary amines with sodium cyanide using vanadium based systems as catalysts.

Sweety Singhal1, Suman L Jain, Bir Sain.   

Abstract

The first report on the use of vanadium-based catalysts for oxidative cyanation of tertiary amines with molecular oxygen in the presence of sodium cyanide and acetic acid to afford the corresponding alpha-aminonitriles in good to excellent yields is described.

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Year:  2009        PMID： 19377689     DOI： 10.1039/b820402k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Vanadium-catalyzed oxidative Strecker reaction: α-C-H cyanation of para-methoxyphenyl (PMP)-protected primary amines.

Authors:  Chen Zhu; Ji-Bao Xia; Chuo Chen
Journal:  Tetrahedron Lett       Date:  2014-01-01       Impact factor: 2.415

2.  A rapid flow strategy for the oxidative cyanation of secondary and tertiary amines via C-H activation.

Authors:  Kidus Tadele; Sanny Verma; Mallikarjuna N Nadagouda; Michael A Gonzalez; Rajender S Varma
Journal:  Sci Rep       Date:  2017-11-24       Impact factor: 4.379

3.  Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation.

Authors:  Franck Le Vaillant; Matthew D Wodrich; Jérôme Waser
Journal:  Chem Sci       Date:  2016-12-22       Impact factor: 9.825

4.  Oxidative cyanation of N-aryltetrahydroisoquinoline induced by visible light for the synthesis of α-aminonitrile using potassium thiocyanate as a "CN" agent.

Authors:  Bing Yi; Ning Yan; Niannian Yi; Yanjun Xie; Xiaoyong Wen; Chak-Tong Au; Donghui Lan
Journal:  RSC Adv       Date:  2019-09-19       Impact factor: 4.036

5.  Oxidative C-H activation of amines using protuberant lychee-like goethite.

Authors:  Sanny Verma; R B Nasir Baig; Mallikarjuna N Nadagouda; Rajender S Varma
Journal:  Sci Rep       Date:  2018-01-31       Impact factor: 4.379
  5 in total

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