Literature DB >> 19361171

Production of a putative iron(V)-oxocorrole species by photo-disproportionation of a bis-corrole-diiron(IV)-mu-oxo dimer: implication for a green oxidation catalyst.

Dilusha N Harischandra1, Gerald Lowery, Rui Zhang, Martin Newcomb.   

Abstract

Photodisproportionation of a bis-corrole-diiron(IV)-mu-oxo dimer gave a corrole-iron(III) species and a corrole-iron(V)-oxo species that can be detected and studied in real time. Air oxidation of the corrole-iron(III) species regenerated the bis-corrole-diiron(IV)-mu-oxo dimer, allowing the development of a photocatalytic method for organic oxidations using molecular oxygen and visible light.

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Year:  2009        PMID： 19361171      PMCID： PMC2720094          DOI： 10.1021/ol900480p

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  18 in total

1.  Chameleon States: High-Valent Metal-Oxo Species of Cytochrome P450 and Its Ruthenium Analogue The research in HU was sponsored by the Binational German Israeli Foundation (GIF) and by the Israeli Ministry of Science, Culture and Sport. Partial support by the US National Science Foundation (CHE-9814301) to J.T.G. is acknowledged. F.O. thanks the EU for a Marie Curie Fellowship.

Authors:  François Ogliaro; Samüel P. de Visser; John T. Groves; Sason Shaik
Journal:  Angew Chem Int Ed Engl       Date:  2001-08-03       Impact factor: 15.336

Review 2.  Corrole-based applications.

Authors:  Iris Aviv; Zeev Gross
Journal:  Chem Commun (Camb)       Date:  2007-05-28       Impact factor: 6.222

3.  Synthesis and characterization of germanium, tin, phosphorus, iron, and rhodium complexes of tris(pentafluorophenyl)corrole, and the utilization of the iron and rhodium corroles as cyclopropanation catalysts.

Authors:  L Simkhovich; A Mahammed; I Goldberg; Z Gross
Journal:  Chemistry       Date:  2001-03-02       Impact factor: 5.236

4.  "True" iron(V) and iron(VI) porphyrins: a first theoretical exploration.

Authors:  Abhishek Dey; Abhik Ghosh
Journal:  J Am Chem Soc       Date:  2002-04-03       Impact factor: 15.419

5.  Theoretical evidence favoring true iron(V)-oxo corrole and corrolazine intermediates.

Authors:  Ingar Wasbotten; Abhik Ghosh
Journal:  Inorg Chem       Date:  2006-06-26       Impact factor: 5.165

6.  Chemical and spectroscopic evidence for an FeV-oxo complex.

Authors:  Filipe Tiago de Oliveira; Arani Chanda; Deboshri Banerjee; Xiaopeng Shan; Sujit Mondal; Lawrence Que; Emile L Bominaar; Eckard Münck; Terrence J Collins
Journal:  Science       Date:  2006-12-21       Impact factor: 47.728

7.  Photocatalytic oxidation of hydrocarbons by a bis-iron(III)-mu-oxo Pacman porphyrin using O2 and visible light.

Authors:  Joel Rosenthal; Thomas D Luckett; Justin M Hodgkiss; Daniel G Nocera
Journal:  J Am Chem Soc       Date:  2006-05-24       Impact factor: 15.419

8.  A phototriggered molecular spring for aerobic catalytic oxidation reactions.

Authors:  Bradford J Pistorio; Christopher J Chang; Daniel G Nocera
Journal:  J Am Chem Soc       Date:  2002-07-10       Impact factor: 15.419

9.  Laser flash photolysis formation and direct kinetic studies of manganese(V)-oxo porphyrin intermediates.

Authors:  Rui Zhang; Martin Newcomb
Journal:  J Am Chem Soc       Date:  2003-10-15       Impact factor: 15.419

10.  Highly reactive porphyrin-iron-oxo derivatives produced by photolyses of metastable porphyrin-iron(IV) diperchlorates.

Authors:  Zhengzheng Pan; Qin Wang; Xin Sheng; John H Horner; Martin Newcomb
Journal:  J Am Chem Soc       Date:  2009-02-25       Impact factor: 15.419
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  7 in total

1.  Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex.

Authors:  Heather M Neu; Jieun Jung; Regina A Baglia; Maxime A Siegler; Kei Ohkubo; Shunichi Fukuzumi; David P Goldberg
Journal:  J Am Chem Soc       Date:  2015-04-03       Impact factor: 15.419

2.  Photocatalytic aerobic oxidation by a bis-porphyrin-ruthenium(IV) mu-oxo dimer: observation of a putative porphyrin-ruthenium(V)-oxo intermediate.

Authors:  Eric Vanover; Yan Huang; Libin Xu; Martin Newcomb; Rui Zhang
Journal:  Org Lett       Date:  2010-05-21       Impact factor: 6.005

3.  Photochemical generation and kinetic studies of a putative porphyrin-ruthenium(V)-oxo species.

Authors:  Rui Zhang; Eric Vanover; Weilong Luo; Martin Newcomb
Journal:  Dalton Trans       Date:  2014-06-21       Impact factor: 4.390

4.  Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex.

Authors:  Jieun Jung; Kei Ohkubo; Katharine A Prokop-Prigge; Heather M Neu; David P Goldberg; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2013-11-12       Impact factor: 5.165

5.  Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.

Authors:  Jieun Jung; Heather M Neu; Pannee Leeladee; Maxime A Siegler; Kei Ohkubo; David P Goldberg; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2016-03-14       Impact factor: 5.165

6.  Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.

Authors:  Regina A Baglia; Jan Paulo T Zaragoza; David P Goldberg
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

7.  Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source.

Authors:  Bittu Chandra; Kundan K Singh; Sayam Sen Gupta
Journal:  Chem Sci       Date:  2017-09-04       Impact factor: 9.825
  7 in total

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