| Literature DB >> 16704240 |
Joel Rosenthal1, Thomas D Luckett, Justin M Hodgkiss, Daniel G Nocera.
Abstract
The C-H bonds of hydrocarbons are oxidized catalytically by the electron-deficient Pacman porphyrin, (DPDF)Fe2O, using visible light and molecular oxygen as the terminal oxidant and oxygen atom source. The photocatalytic reactions proceed under mild conditions (ambient temperature and pressure) without the need for an external co-reductant.Entities:
Year: 2006 PMID: 16704240 DOI: 10.1021/ja058731s
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419