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Literature DB >> 19353606

A spherical molecule with a carbon-free I(h)-C80 topological framework.

Manfred Scheer¹, Andrea Schindler, Christian Gröger, Alexander V Virovets, Eugenia V Peresypkina.

Abstract

The complete encapsulation of ortho-carborane by a fullerene-like building-block system consisting of pentaphosphaferrocene and Cu(I)Cl leads to the formation of the spherical supermolecule C(2)B(10)H(12) section sign[{Cp*Fe(eta(5)-P(5))}(12)(CuCl)(20)]. This product of template-controlled aggregation represents the first example of a carbon-free C(80) analogue possessing icosahedral symmetry.

Entities: Chemical

Year: 2009 PMID： 19353606 DOI： 10.1002/anie.200900342

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

18 in total

1. Assembly of silver Trigons into a buckyball-like Ag₁₈₀ nanocage.

Authors: Zhi Wang; Hai-Feng Su; Yuan-Zhi Tan; Stan Schein; Shui-Chao Lin; Wei Liu; Shu-Ao Wang; Wen-Guang Wang; Chen-Ho Tung; Di Sun; Lan-Sun Zheng
Journal: Proc Natl Acad Sci U S A Date: 2017-10-27 Impact factor: 11.205

2. The Missing Parent Compound [(C₅ H₅ )Fe(η⁵ -P₅ )]: Synthesis, Characterization, Coordination Behavior and Encapsulation.

Authors: Claudia Heinl; Eugenia Peresypkina; Gábor Balázs; Eric Mädl; Alexander V Virovets; Manfred Scheer
Journal: Chemistry Date: 2021-03-11 Impact factor: 5.236

3. 1,2,4-Triphospholyl anions - versatile building blocks for the formation of 1D, 2D and 3D assemblies.

Authors: Claudia Heindl; Eugenia V Peresypkina; Alexander V Virovets; Vladislav Yu Komarov; Manfred Scheer
Journal: Dalton Trans Date: 2015-06-14 Impact factor: 4.390

4. Supramolecular Synthons: Will Giant Rigid Superspheres Do?

Authors: Eugenia Peresypkina; Alexander Virovets; Manfred Scheer
Journal: Cryst Growth Des Date: 2016-02-23 Impact factor: 4.076

5. An Inverted-Sandwich Diuranium μ-η⁵:η⁵-Cyclo-P₅ Complex Supported by U-P₅ δ-Bonding.

Authors: Benedict M Gardner; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Angew Chem Weinheim Bergstr Ger Date: 2015-04-27

6. The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²-P₂)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers.

Authors: Mehdi Elsayed Moussa; Bianca Attenberger; Martin Fleischmann; Andrea Schreiner; Manfred Scheer
Journal: Eur J Inorg Chem Date: 2016-08-29 Impact factor: 2.524

A spherical molecule with a carbon-free I(h)-C80 topological framework.

1. Assembly of silver Trigons into a buckyball-like Ag₁₈₀ nanocage.

2. The Missing Parent Compound [(C₅ H₅ )Fe(η⁵ -P₅ )]: Synthesis, Characterization, Coordination Behavior and Encapsulation.

3. 1,2,4-Triphospholyl anions - versatile building blocks for the formation of 1D, 2D and 3D assemblies.

4. Supramolecular Synthons: Will Giant Rigid Superspheres Do?

5. An Inverted-Sandwich Diuranium μ-η⁵:η⁵-Cyclo-P₅ Complex Supported by U-P₅ δ-Bonding.

6. The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²-P₂)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers.

7. An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P5 Complex Supported by U-P5 δ-Bonding.

8. Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P5)}24Cu96Br96] Derived from Pentaphosphaferrocene and CuBr2.

9. A nano-sized supramolecule beyond the fullerene topology.

10. Giant Spherical Cluster with I-C140 Fullerene Topology.