Literature DB >> 19341307

C-H bond activation of decamethylcobaltocene mediated by a nitrogenase Fe(8)S(7) P-cluster model.

Yasuhiro Ohki1, Ayuro Murata, Motosuke Imada, Kazuyuki Tatsumi.   

Abstract

A C-H bond of Cp*(2)Co was found to be cleaved by a [Fe(8)S(7)] cluster model of the nitrogenase P-cluster. This is the first example of C-H bond activation mediated by a biologically relevant Fe/S cluster. The reaction mechanism probably consists of electron transfer from Cp*(2)Co to the [Fe(8)S(7)] cluster and subsequent proton abstraction by the reduced form of the cluster.

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Year:  2009        PMID： 19341307     DOI： 10.1021/ic900284f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  6 in total

1.  Synthetic analogues of [Fe4S4(Cys)3(His)] in hydrogenases and [Fe4S4(Cys)4] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)2}4].

Authors:  Yasuhiro Ohki; Kazuki Tanifuji; Norihiro Yamada; Motosuke Imada; Tomoyuki Tajima; Kazuyuki Tatsumi
Journal:  Proc Natl Acad Sci U S A       Date:  2011-07-18       Impact factor: 11.205

2.  Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes.

Authors:  Daniël L J Broere; Brandon Q Mercado; James T Lukens; Avery C Vilbert; Gourab Banerjee; Hannah M C Lant; Shin Hee Lee; Eckhard Bill; Stephen Sproules; Kyle M Lancaster; Patrick L Holland
Journal:  Chemistry       Date:  2018-06-07       Impact factor: 5.236

3.  Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia.

Authors:  K Cory MacLeod; Sean F McWilliams; Brandon Q Mercado; Patrick L Holland
Journal:  Chem Sci       Date:  2016-06-14       Impact factor: 9.825

4.  Reversible On/Off Switching of Lactide Cyclopolymerization with a Redox-Active Formazanate Ligand.

Authors:  Folkert de Vries; Edwin Otten
Journal:  ACS Catal       Date:  2022-03-21       Impact factor: 13.084

5.  Statistical analysis of PN clusters in Mo/VFe protein crystals using a bond valence method toward their electronic structures.

Authors:  Chang Yuan; Wan-Ting Jin; Zhao-Hui Zhou
Journal:  RSC Adv       Date:  2022-02-11       Impact factor: 3.361

6.  A Synthetic Model of Enzymatic [Fe4S4]-Alkyl Intermediates.

Authors:  Mengshan Ye; Niklas B Thompson; Alexandra C Brown; Daniel L M Suess
Journal:  J Am Chem Soc       Date:  2019-08-16       Impact factor: 15.419
  6 in total

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