Literature DB >> 19338007

Conversion of carbon dioxide into methanol with silanes over N-heterocyclic carbene catalysts.

Siti Nurhanna Riduan1, Yugen Zhang, Jackie Y Ying.   

Abstract

Activate and reduce: Carbon dioxide was reduced with silane using a stable N-heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition-metal catalysts for this reaction. This approach offers a very promising protocol for chemical CO(2) activation and fixation.

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Year:  2009        PMID： 19338007     DOI： 10.1002/anie.200806058

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  21 in total

1.  Chemical bonding: Rethinking carbon.

Authors:  C Adam Dyker; Guy Bertrand
Journal:  Nat Chem       Date:  2009-07       Impact factor: 24.427

2.  Copper- and copper-N-heterocyclic carbene-catalyzed C-H activating carboxylation of terminal alkynes with CO2 at ambient conditions.

Authors:  Dingyi Yu; Yugen Zhang
Journal:  Proc Natl Acad Sci U S A       Date:  2010-11-08       Impact factor: 11.205

3.  On the role of CO2 in NHC-catalyzed oxidation of aldehydes.

Authors:  Pei-Chen Chiang; Jeffrey W Bode
Journal:  Org Lett       Date:  2011-04-12       Impact factor: 6.005

4.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

5.  Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.

Authors:  Eugenia Aldeco-Perez; Amos J Rosenthal; Bruno Donnadieu; Pattiyil Parameswaran; Gernot Frenking; Guy Bertrand
Journal:  Science       Date:  2009-10-23       Impact factor: 47.728

6.  Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts.

Authors:  Glenn Kuchenbeiser; Michele Soleilhavoup; Bruno Donnadieu; Guy Bertrand
Journal:  Chem Asian J       Date:  2009-11-02

7.  Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Authors:  Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

8.  Heterogeneous reduction of carbon dioxide by hydride-terminated silicon nanocrystals.

Authors:  Wei Sun; Chenxi Qian; Le He; Kulbir Kaur Ghuman; Annabelle P Y Wong; Jia Jia; Abdinoor A Jelle; Paul G O'Brien; Laura M Reyes; Thomas E Wood; Amr S Helmy; Charles A Mims; Chandra Veer Singh; Geoffrey A Ozin
Journal:  Nat Commun       Date:  2016-08-23       Impact factor: 14.919

9.  A Porous Metal-Organic Framework Assembled by [Cu30] Nanocages: Serving as Recyclable Catalysts for CO2 Fixation with Aziridines.

Authors:  Hang Xu; Xiao-Fang Liu; Chun-Shuai Cao; Bin Zhao; Peng Cheng; Liang-Nian He
Journal:  Adv Sci (Weinh)       Date:  2016-05-17       Impact factor: 16.806

Review 10.  From CO2 activation to catalytic reduction: a metal-free approach.

Authors:  Sreejyothi P; Swadhin K Mandal
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825
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