Literature DB >> 21486084

On the role of CO2 in NHC-catalyzed oxidation of aldehydes.

Pei-Chen Chiang1, Jeffrey W Bode.   

Abstract

NHC-catalyzed oxidations using carbon dioxide as the stoichiometric oxidant have been carefully investigated. These studies support a secondary role of CO(2) in suppressing side reactions and exogenous oxygen as the actual oxidant.

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Year:  2011        PMID： 21486084      PMCID： PMC3100891          DOI： 10.1021/ol2006538

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  25 in total

1.  Reversible carboxylation of N-heterocyclic carbenes.

Authors:  Hung A Duong; Thomas N Tekavec; Atta M Arif; Janis Louie
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2.  NHC catalyzed transformation of aromatic aldehydes to acids by carbon dioxide: an unexpected reaction.

Authors:  Vijay Nair; Vimal Varghese; Rony Rajan Paul; Anu Jose; C R Sinu; Rajeev S Menon
Journal:  Org Lett       Date:  2010-06-04       Impact factor: 6.005

3.  N-heterocyclic carbene catalyzed C--C bond cleavage in redox esterifications of chiral formylcyclopropanes.

Authors:  Stephanie S Sohn; Jeffrey W Bode
Journal:  Angew Chem Int Ed Engl       Date:  2006-09-11       Impact factor: 15.336

4.  Enantioselective, cyclopentene-forming annulations via NHC-catalyzed benzoin-oxy-cope reactions.

Authors:  Pei-Chen Chiang; Juthanat Kaeobamrung; Jeffrey W Bode
Journal:  J Am Chem Soc       Date:  2007-03-03       Impact factor: 15.419

5.  NHC-catalyzed oxidative cyclization reactions of 2-alkynylbenzaldehydes under aerobic conditions: synthesis of O-heterocycles.

Authors:  Jong Hyub Park; Sachin V Bhilare; So Won Youn
Journal:  Org Lett       Date:  2011-03-29       Impact factor: 6.005

Review 6.  Turning carbon dioxide into fuel.

Authors:  Z Jiang; T Xiao; V L Kuznetsov; P P Edwards
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2010-07-28       Impact factor: 4.226

7.  N-heterocyclic carbene-catalyzed generation of homoenolates: gamma-butyrolactones by direct annulations of enals and aldehydes.

Authors:  Stephanie S Sohn; Evelyn L Rosen; Jeffrey W Bode
Journal:  J Am Chem Soc       Date:  2004-11-10       Impact factor: 15.419

8.  A systematic investigation of factors influencing the decarboxylation of imidazolium carboxylates.

Authors:  Bret R Van Ausdall; Jeremy L Glass; Kelly M Wiggins; Atta M Aarif; Janis Louie
Journal:  J Org Chem       Date:  2009-10-16       Impact factor: 4.354

9.  NHC catalyzed oxidations of aldehydes to esters: chemoselective acylation of alcohols in presence of amines.

Authors:  Suman De Sarkar; Stefan Grimme; Armido Studer
Journal:  J Am Chem Soc       Date:  2010-02-03       Impact factor: 15.419

10.  CO2 adducts of N-heterocyclic carbenes: thermal stability and catalytic activity toward the coupling of CO2 with epoxides.

Authors:  Hui Zhou; Wen-Zhen Zhang; Cui-Hua Liu; Jing-Ping Qu; Xiao-Bing Lu
Journal:  J Org Chem       Date:  2008-09-13       Impact factor: 4.354
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  6 in total

1.  Chiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.

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Journal:  ACS Catal       Date:  2012-02-29       Impact factor: 13.084

2.  The effect of the N-mesityl group in NHC-catalyzed reactions.

Authors:  Jessada Mahatthananchai; Jeffrey W Bode
Journal:  Chem Sci       Date:  2012-01-01       Impact factor: 9.825

3.  Synthesis of enantiomerically pure N-(2,3-dihydroxypropyl)arylamides via oxidative esterification.

Authors:  Akula Raghunadh; Satish S More; T Krishna Chaitanya; Yadla Sateesh Kumar; Suresh Babu Meruva; L Vaikunta Rao; U K Syam Kumar
Journal:  Beilstein J Org Chem       Date:  2013-10-17       Impact factor: 2.883

4.  Carbon-carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone.

Authors:  Bao-Sheng Li; Yuhuang Wang; Zhichao Jin; Pengcheng Zheng; Rakesh Ganguly; Yonggui Robin Chi
Journal:  Nat Commun       Date:  2015-02-05       Impact factor: 14.919

5.  Characteristics and hazards of the cinnamaldehyde oxidation process.

Authors:  Chang Yu; Yuan-Lin Li; Min Liang; Su-Yi Dai; Li Ma; Wei-Guang Li; Fang Lai; Xiong-Min Liu
Journal:  RSC Adv       Date:  2020-05-20       Impact factor: 4.036

6.  NHC-catalysed highly selective aerobic oxidation of nonactivated aldehydes.

Authors:  Lennart Möhlmann; Stefan Ludwig; Siegfried Blechert
Journal:  Beilstein J Org Chem       Date:  2013-03-22       Impact factor: 2.883
  6 in total

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