Levels and vertical distributions of PCBs, PBDEs, and OCPs in the atmospheric boundary layer: observation from the Beijing 325-m meteorological tower.

Polyurethane foam disk passive air sampling was carried out to investigate the levels, vertical distributions, and potential sources of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and organochlorine pesticides (OCPs) in the atmospheric boundary layer of an urban site in Asia. Sampling was performed at nine heights (15, 47, 80, 120, 160, 200, 240, 280, 320 m) of the 325-m meteorological tower in Beijing, China over three 2-month periods between December 2006 and August 2007. This is the first study to report vertical variations of PBDEs in the ABL and one of only a few studies to investigate vertical distributions of persistent organic pollutants. The levels of sigma19PCBs and sigma8PBDEs were relatively low, ranging from 22 to 65 and from 2.3 to 18 pg m(-3), respectively. Air concentrations of gamma-HCH were high, with values in the range of 39-103 pg m(-3) in winter, 100-180 pg m(-3) in spring, and 115-242 pg m(-3) in summer, respectively. alpha-HCH concentrations ranged from 20 to 86 pg m(-3), p,p'-DDT between 7.3 and 78 pg m(-3), and HCB between 15 and 160 pg m(-3). The seasonal variations of PCBs, PBDEs, and OCPs may reflect different sources for these chemicals, such as those related with regional use (gamma-HCH), volatilization/re-emission (PBDEs, PCBs, alpha-HCH), and pesticide impurities (HCB). Although the performance reference compounds (PRCs) were spiked before deployment, the sampling rates showed strong dependency on wind speeds, resulting in large variations in uptake rates in the ABL, ranging from approximately 7.0 m3 day(-1) at ground level to 11 m3 day(-1) at 320 m. Levels of PCBs, PBDEs, and OCPs decreased with increasing ABL height indicating the potential of Beijing as the local sources.