Emissions, environmental levels, sources, formation pathways, and analysis of polybrominated dibenzo-p-dioxins and dibenzofurans: a review.

Polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) were labeled potential persistent organic pollutants by the Stockholm Convention and have structures and toxicities similar to those of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), which has caused considerable concern. This article reviews the current available literature on the status, sources, formation pathways, and analysis of PBDD/Fs. PBDD/Fs are widely generated in industrial thermal processes, such as those for brominated flame retardant (BFR) products, e-waste dismantling, metal smelting processes, and waste incineration. PBDD/Fs can form via the following routes: precursor formation, de novo formation, biosynthesis, and natural formation. The levels of PBDD/Fs in the environment and in organisms and humans have increased due to extensive consumption and the increasing inventory of BFRs; thus, the risk of human exposure to PBDD/Fs is expected to be high.