| Literature DB >> 19271705 |
Abraham M Shultz1, Omar K Farha, Joseph T Hupp, SonBinh T Nguyen.
Abstract
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl)benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.Entities:
Year: 2009 PMID: 19271705 DOI: 10.1021/ja900203f
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419