Literature DB >> 19191361

[Co@Ge10]3-: an intermetalloid cluster with archimedean pentagonal prismatic structure.

Jian-Qiang Wang1, Saskia Stegmaier, Thomas F Fässler.   

Abstract

Inorganic pentaprismane: The unusual structure of the anion [Co@Ge(10)](3-), which was obtained by the reaction of K(4)Ge(9) with [Co(C(8)H(12))(C(8)H(13))] in ethylenediamine, raises questions about chemical bonding in the anion. The Zintl ion cluster has virtual D(5h) symmetry and is a unique example of a ligand-free cluster that is not a deltahedron. The delocalized chemical bonding is represented in the picture by one of the bonding orbitals of the anion.

Entities:  

Year:  2009        PMID： 19191361     DOI： 10.1002/anie.200805511

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  12 in total

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4.  A remarkable mixture of germanium with phosphorus and arsenic atoms making stable pentagonal hetero-prisms [M@Ge5E5]+, E = P, As and M = Fe, Ru, Os.

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6.  Probing the structural evolution of ruthenium doped germanium clusters: Photoelectron spectroscopy and density functional theory calculations.

Authors:  Yuanyuan Jin; Shengjie Lu; Andreas Hermann; Xiaoyu Kuang; Chuanzhao Zhang; Cheng Lu; Hongguang Xu; Weijun Zheng
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7.  Metallocages for Metal Anions: Highly Charged [Co@Ge9 ]5- and [Ru@Sn9 ]6- Clusters Featuring Spherically Encapsulated Co1- and Ru2- Anions.

Authors:  Benedikt J L Witzel; Wilhelm Klein; Jasmin V Dums; Marina Boyko; Thomas F Fässler
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-21       Impact factor: 15.336

8.  Understanding of multimetallic cluster growth.

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Journal:  Nat Commun       Date:  2016-01-25       Impact factor: 14.919

9.  Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals.

Authors:  R Bruce King
Journal:  Molecules       Date:  2020-07-08       Impact factor: 4.411

10.  Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3-, [Rh@Sn12]3-, [Rh2@Sn17]6- and the first triply-fused stannide, [Rh3@Sn24]5.

Authors:  Chao Liu; Xiao Jin; Lei-Jiao Li; Jun Xu; John E McGrady; Zhong-Ming Sun
Journal:  Chem Sci       Date:  2019-03-11       Impact factor: 9.825
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