Literature DB >> 19123205

Stable five-membered-ring allenes with second-row elements only: not allenes, but zwitterions.

Manfred Christl, Bernd Engels.   

Abstract

A pyrazole derivative, considered as the stable five-membered cyclic allene 1 a by Dyker, Bertrand, et al., is reinterpreted to be a zwitterion 1 b. It is shown that the bonding characteristics typical for an allene are not possible for structure 1 a. Ar = 2,6-dimethylphenyl.

Entities:  

Year:  2009        PMID： 19123205     DOI： 10.1002/anie.200803476

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Coordination chemistry at carbon.

Authors:  Manuel Alcarazo; Christian W Lehmann; Anakuthil Anoop; Walter Thiel; Alois Fürstner
Journal:  Nat Chem       Date:  2009-06-14       Impact factor: 24.427

Review 2.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

3.  Carbene derived diradicaloids - building blocks for singlet fission?

Authors:  Julian Messelberger; Annette Grünwald; Piermaria Pinter; Max M Hansmann; Dominik Munz
Journal:  Chem Sci       Date:  2018-07-02       Impact factor: 9.825
  3 in total

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