Electrical conductivity and cation exchange kinetic studies on poly-o-toluidine Th(IV) phosphate nano-composite cation exchange material.

An advanced organic-inorganic cation exchange material poly-o-toluidine Th(IV) phosphate nano-composite was synthesized by a modified sol-gel technique by incorporating Th(IV) phosphate precipitate with the matrix of poly-o-toluidine. The material showed good ion-exchange behavior and used successfully in separation of metal ions. The conductivity of the composite was found within the range of 10(-2) to 10(-3)S/cm; measured by 4-in-line-probe dc electrical conductivity measuring technique. The conductivity is at the border of metallic and semiconductor region. Ion-exchange kinetics for few divalent metal ions was evaluated by particle diffusion-controlled ion-exchange phenomenon at four different temperatures. The particle diffusion mechanism is confirmed by the linear tau (dimensionless time parameter) versus t (time) plots. The exchange processes thus controlled by the diffusion within the exchanger particle for the systems studies herein. Some physical parameters like self-diffusion coefficient (D(0))(,) energy of activation (E(a)) and entropy of activation (DeltaS(0)) have been evaluated under conditions favoring a particle diffusion-controlled mechanism.