Literature DB >> 19030554

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers.

Huadong Wang1, Roland Fröhlich, Gerald Kehr, Gerhard Erker.   

Abstract

The "frustrated Lewis pair" 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 reversibly activates dihydrogen; it serves as an active catalyst for the hydrogenation of silyl enol ethers under mild reaction conditions.

Entities:  

Year:  2008        PMID： 19030554     DOI： 10.1039/b813286k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

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Journal:  Chemistry       Date:  2020-03-11       Impact factor: 5.236

3.  Exploring the Reactivity of B-Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System.

Authors:  Jan Schulz; Menyhárt B Sárosi; Evamarie Hey-Hawkins
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4.  Crystal structure of (n-but-yl)[2-(2,6-di-meth-oxy-phen-yl)-6-methyl-phen-yl](2-meth-oxy-phen-yl)phospho-nium chloride monohydrate.

Authors:  Ge Feng; Alexander S Filatov; Richard F Jordan
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-01-13

5.  Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

Authors:  Gabriella Skara; Freija De Vleeschouwer; Paul Geerlings; Frank De Proft; Balazs Pinter
Journal:  Sci Rep       Date:  2017-11-22       Impact factor: 4.379

6.  A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.

Authors:  Jeffrey M Farrell; Roy T Posaratnanathan; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-01-26       Impact factor: 9.825

7.  FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers.

Authors:  Imtiaz Khan; Benjamin G Reed-Berendt; Rebecca L Melen; Louis C Morrill
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-24       Impact factor: 15.336

8.  A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis-Pair and Reductive Elimination.

Authors:  Philipp Holtkamp; Jan Schwabedissen; Beate Neumann; Hans-Georg Stammler; Igor V Koptyug; Vladimir V Zhivonitko; Norbert W Mitzel
Journal:  Chemistry       Date:  2020-11-23       Impact factor: 5.236
  8 in total

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