Literature DB >> 18998690

Nickel-catalyzed alkenylation and alkylation of fluoroarenes via activation of C-H bond over C-F bond.

Yoshiaki Nakao1, Natsuko Kashihara, Kyalo Stephen Kanyiva, Tamejiro Hiyama.   

Abstract

Nickel/P(c-C(5)H(9))(3) (PCyp(3)) catalyst effects the addition reactions of fluoroarenes across alkynes, 1,3-dienes, and vinylarenes via the activation of C-H bonds over C-F bonds. The acidic C-H bonds located ortho to fluorine are exclusively activated to afford a range of alkenylated and alkylated fluoroarenes.

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Year:  2008        PMID： 18998690     DOI： 10.1021/ja807258m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Rh(I)-catalyzed direct arylation of azines.

Authors:  Ashley M Berman; Robert G Bergman; Jonathan A Ellman
Journal:  J Org Chem       Date:  2010-10-29       Impact factor: 4.354

2.  Cobalt-catalyzed, aminoquinoline-directed C(sp²)-H bond alkenylation by alkynes.

Authors:  Liene Grigorjeva; Olafs Daugulis
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-24       Impact factor: 15.336

3.  Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp2)-H bonds.

Authors:  Shao-Long Qi; Yu-Peng Liu; Yi Li; Yu-Xin Luan; Mengchun Ye
Journal:  Nat Commun       Date:  2022-05-26       Impact factor: 17.694

4.  Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C-H Bonds.

Authors:  Tung Thanh Nguyen; Liene Grigorjeva; Olafs Daugulis
Journal:  ACS Catal       Date:  2015-12-22       Impact factor: 13.084

5.  Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.

Authors:  David E Stephens; Oleg V Larionov
Journal:  Tetrahedron       Date:  2015-08-19       Impact factor: 2.457

6.  Activation of Aromatic C-F Bonds by a N-Heterocyclic Olefin (NHO).

Authors:  Debdeep Mandal; Shubhadeep Chandra; Nicolás I Neuman; Alok Mahata; Arighna Sarkar; Abhinanda Kundu; Srinivas Anga; Hemant Rawat; Carola Schulzke; Kaustubh R Mote; Biprajit Sarkar; Vadapalli Chandrasekhar; Anukul Jana
Journal:  Chemistry       Date:  2020-04-28       Impact factor: 5.236

7.  Adsorption of Polycyclic Aromatic Hydrocarbons and C60 onto Forsterite: C-H Bond Activation by the Schottky Vacancy.

Authors:  Dario Campisi; Thanja Lamberts; Nelson Y Dzade; Rocco Martinazzo; Inge Loes Ten Kate; Alexander G G M Tielens
Journal:  ACS Earth Space Chem       Date:  2022-07-27       Impact factor: 3.556

8.  Cobalt(III)-catalyzed synthesis of indazoles and furans by C-H bond functionalization/addition/cyclization cascades.

Authors:  Joshua R Hummel; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2014-12-24       Impact factor: 15.419

9.  Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives.

Authors:  Kotaro Kikushima; Haruka Koyama; Kazuki Kodama; Toshifumi Dohi
Journal:  Molecules       Date:  2021-03-04       Impact factor: 4.411
  9 in total

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