Literature DB >> 18997950

Sn(iv) phosphonates as catalysts in solvent-free Baeyer-Villiger oxidations using H(2)O(2).

Sharath Kirumakki1, Sandani Samarajeewa, Robert Harwell, Atashi Mukherjee, Rolfe H Herber, Abraham Clearfield.   

Abstract

We have designed a new family of layered Sn(iv)phosphonate (SnPP) materials which are very efficient catalysts in the BV oxidation of aromatic aldehydes without any solvent and using aqueous H(2)O(2) (30%) as the oxidant.

Entities:  

Year:  2008        PMID: 18997950     DOI: 10.1039/b807938b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  In situ deca-rbonylation of N,N-di-methyl-formamide to form di-methyl-ammonium cations in the hybrid framework compound {[(CH3)2NH2]2[Zn{O3PC6H2(OH)2PO3}]} n.

Authors:  Josemaria S Soriano; Bryan E Galeas; Paul Garrett; Ryan A Flores; Juan L Pinedo; Tsuyoshi A Kohlgruber; Daniel Felton; Pius O Adelani
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2019-09-27
  1 in total

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