Literature DB >> 18985205

Unprecedented steric deformation of ortho-carborane.

Brian W Hutton1, Fraser MacIntosh, David Ellis, Fabien Herisse, Stuart A Macgregor, David McKay, Victoria Petrie-Armstrong, Georgina M Rosair, Dmitry S Perekalin, Hugo Tricas, Alan J Welch.   

Abstract

The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities.

Entities:  

Year:  2008        PMID： 18985205     DOI： 10.1039/b810702e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  2-[(Cyclo-penta-1,3-dien-2-yl)diphenyl-meth-yl]-1-methyl-1H-imidazole.

Authors:  Qi Sun; Wanli Nie; Maxim V Borzov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-01-09

2.  Isomerisation of nido-[C2B10H12]2- dianions: unprecedented rearrangements and new structural motifs in carborane cluster chemistry.

Authors:  David McKay; Stuart A Macgregor; Alan J Welch
Journal:  Chem Sci       Date:  2015-03-24       Impact factor: 9.825

3.  Crystal structures of the carborane dianions [1,4-(PhCB₁₀H₁₀C)₂C₆H₄]²⁻ and [1,4-(PhCB₁₀H₁₀C)₂C₆F₄]²⁻ and the stabilizing role of the para-phenylene unit on 2n+3 skeletal electron clusters.

Authors:  Jan Kahlert; Hans-Georg Stammler; Beate Neumann; Rachel A Harder; Lothar Weber; Mark A Fox
Journal:  Angew Chem Int Ed Engl       Date:  2014-02-26       Impact factor: 15.336
  3 in total

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