Literature DB >> 18959401

Synthesis and reaction of fullerene C70 encapsulating two molecules of H2.

Michihisa Murata1, Shuhei Maeda, Yuta Morinaka, Yasujiro Murata, Koichi Komatsu.   

Abstract

New endohedral fullerene C(70) encapsulating one and two H(2) molecule(s) has been synthesized by organic reactions, the so-called "molecular surgery" method, and the first organic derivatization of H(2)@C(70) and (H(2))(2)@C(70) has been conducted. Although the interaction between inner H(2) and outer C(70) is rather weak, (H(2))(2)@C(70) exhibits smaller equilibrium constants in the Diels-Alder reaction with 9,10-dimethylanthracene than those of H(2)@C(70).

Entities:  

Year:  2008        PMID： 18959401     DOI： 10.1021/ja8076846

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  A computational study on the endohedral alkali metal and ion B40 nanocluster.

Authors:  Zahra Rostami; Fatemeh Firoznasab
Journal:  J Mol Model       Date:  2018-07-05       Impact factor: 1.810

2.  Sc3CH@C80: selective (13)C enrichment of the central carbon atom.

Authors:  Katrin Junghans; Marco Rosenkranz; Alexey A Popov
Journal:  Chem Commun (Camb)       Date:  2016-05-05       Impact factor: 6.222

3.  The dipolar endofullerene HF@C60.

Authors:  Andrea Krachmalnicoff; Richard Bounds; Salvatore Mamone; Shamim Alom; Maria Concistrè; Benno Meier; Karel Kouřil; Mark E Light; Mark R Johnson; Stéphane Rols; Anthony J Horsewill; Anna Shugai; Urmas Nagel; Toomas Rõõm; Marina Carravetta; Malcolm H Levitt; Richard J Whitby
Journal:  Nat Chem       Date:  2016-07-11       Impact factor: 24.427

4.  Synthesis of a distinct water dimer inside fullerene C70.

Authors:  Rui Zhang; Michihisa Murata; Tomoko Aharen; Atsushi Wakamiya; Takafumi Shimoaka; Takeshi Hasegawa; Yasujiro Murata
Journal:  Nat Chem       Date:  2016-03-07       Impact factor: 24.427

5.  X-ray observation of a helium atom and placing a nitrogen atom inside He@C60 and He@C70.

Authors:  Yuta Morinaka; Satoru Sato; Atsushi Wakamiya; Hidefumi Nikawa; Naomi Mizorogi; Fumiyuki Tanabe; Michihisa Murata; Koichi Komatsu; Ko Furukawa; Tatsuhisa Kato; Shigeru Nagase; Takeshi Akasaka; Yasujiro Murata
Journal:  Nat Commun       Date:  2013       Impact factor: 14.919

6.  Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane.

Authors:  Sally Bloodworth; John Gräsvik; Shamim Alom; Karel Kouřil; Stuart J Elliott; Neil J Wells; Anthony J Horsewill; Salvatore Mamone; Mónica Jiménez-Ruiz; Stéphane Rols; Urmas Nagel; Toomas Rõõm; Malcolm H Levitt; Richard J Whitby
Journal:  Chemphyschem       Date:  2018-01-04       Impact factor: 3.102

7.  First Synthesis and Characterization of CH4 @C60.

Authors:  Sally Bloodworth; Gabriela Sitinova; Shamim Alom; Sara Vidal; George R Bacanu; Stuart J Elliott; Mark E Light; Julie M Herniman; G John Langley; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-12       Impact factor: 15.336

8.  Nuclear magnetic resonance of hydrogen molecules trapped inside C70 fullerene cages.

Authors:  Salvatore Mamone; Maria Concistrè; Ivo Heinmaa; Marina Carravetta; Ilya Kuprov; Gary Wall; Mark Denning; Xuegong Lei; Judy Y-C Chen; Yongjun Li; Yasujiro Murata; Nicholas J Turro; Malcolm H Levitt
Journal:  Chemphyschem       Date:  2013-06-20       Impact factor: 3.102

9.  Isolation of the simplest hydrated acid.

Authors:  Rui Zhang; Michihisa Murata; Atsushi Wakamiya; Takafumi Shimoaka; Takeshi Hasegawa; Yasujiro Murata
Journal:  Sci Adv       Date:  2017-04-21       Impact factor: 14.136

10.  Encapsulation of Hydrogen Molecules in C50 Fullerene: An ab Initio Study of Structural, Energetic, and Electronic Properties of H2@C50 and 2H2@C50 Complexes.

Authors:  Alireza Zeinalinezhad; Riadh Sahnoun
Journal:  ACS Omega       Date:  2020-05-22
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