| Literature DB >> 18937460 |
Yuzhong Wang1, Yaoming Xie, Pingrong Wei, R Bruce King, Henry F Schaefer, Paul v R Schleyer, Gregory H Robinson.
Abstract
The potassium graphite reduction of L:PCl3 leads to the formation of carbene-stabilized diphosphorus molecules, L:P-P:L, 1 (L: = :C{N(2,6-Pri2C6H3)CH}2) and 2 (L: = :C{N(2,4,6-Me3C6H2)CH}2), respectively. The nature of the bonding in 1 and 2 was delineated by DFT computations.Entities:
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Year: 2008 PMID： 18937460 DOI： 10.1021/ja807828t
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419