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Literature DB >> 18798182

An inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+.

Kallol Ray¹, Jason England, Adam T Fiedler, Marlène Martinho, Eckard Münck, Lawrence Que.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2008 PMID： 18798182 PMCID： PMC2656284 DOI： 10.1002/anie.200802219

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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16 in total

1. Geometric and electronic structure/function correlations in non-heme iron enzymes.

Authors: E I Solomon; T C Brunold; M I Davis; J N Kemsley; S K Lee; N Lehnert; F Neese; A J Skulan; Y S Yang; J Zhou
Journal: Chem Rev Date: 2000-01-12 Impact factor: 60.622

Review 2. Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.

Authors: Miquel Costas; Mark P Mehn; Michael P Jensen; Lawrence Que
Journal: Chem Rev Date: 2004-02 Impact factor: 60.622

Review 3. Reaction mechanisms of mononuclear non-heme iron oxygenases.

Authors: Mahdi M Abu-Omar; Aristobulo Loaiza; Nikos Hontzeas
Journal: Chem Rev Date: 2005-06 Impact factor: 60.622

Review 4. High-valent nonheme iron-oxo species in biomimetic oxidations.

Authors: Xiaopeng Shan; Lawrence Que
Journal: J Inorg Biochem Date: 2006-03-13 Impact factor: 4.155

Review 5. The road to non-heme oxoferryls and beyond.

Authors: Lawrence Que
Journal: Acc Chem Res Date: 2007-06-27 Impact factor: 22.384

6. Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center.

Authors: Na Young Oh; Mi Sook Seo; Mi Hee Lim; Mark B Consugar; Mi Joo Park; Jan-Uwe Rohde; Jaehong Han; Kwan Mook Kim; Jinheung Kim; Lawrence Que; Wonwoo Nam
Journal: Chem Commun (Camb) Date: 2005-10-20 Impact factor: 6.222

7. Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins.

Authors: Yumi Suh; Mi Sook Seo; Kwan Mook Kim; Youn Sang Kim; Ho G Jang; Takehiko Tosha; Teizo Kitagawa; Jinheung Kim; Wonwoo Nam
Journal: J Inorg Biochem Date: 2006-02-03 Impact factor: 4.155

8. Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex.

Authors: Jan-Uwe Rohde; Jun-Hee In; Mi Hee Lim; William W Brennessel; Michael R Bukowski; Audria Stubna; Eckard Münck; Wonwoo Nam; Lawrence Que
Journal: Science Date: 2003-02-14 Impact factor: 47.728

9. Synthesis, structure determination, and spectroscopic/computational characterization of a series of Fe(II)-thiolate model complexes: implications for Fe-S bonding in superoxide reductases.

Authors: Adam T Fiedler; Heather L Halfen; Jason A Halfen; Thomas C Brunold
Journal: J Am Chem Soc Date: 2005-02-16 Impact factor: 15.419

10. Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex.

Authors: Andrea Decker; Jan-Uwe Rohde; Lawrence Que; Edward I Solomon
Journal: J Am Chem Soc Date: 2004-05-05 Impact factor: 15.419

8 in total

1. Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.

Authors: Shunichi Fukuzumi; Yuma Morimoto; Hiroaki Kotani; Pance Naumov; Yong-Min Lee; Wonwoo Nam
Journal: Nat Chem Date: 2010-07-11 Impact factor: 24.427

2. Steric hindrance effect of the equatorial ligand on Fe(IV)O and Ru(IV)O complexes: a density functional study.

Authors: Yi Wang; Keli Han
Journal: J Biol Inorg Chem Date: 2010-03 Impact factor: 3.358

3. Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.

Authors: Anna Company; Irene Prat; Jonathan R Frisch; Ruben Mas-Ballesté; Mireia Güell; Gergely Juhász; Xavi Ribas; Eckard Münck; Josep M Luis; Lawrence Que; Miquel Costas
Journal: Chemistry Date: 2011-01-05 Impact factor: 5.236

4. [Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.

Authors: Samuel A Wilson; Junying Chen; Seungwoo Hong; Yong-Min Lee; Martin Clémancey; Ricardo Garcia-Serres; Takashi Nomura; Takashi Ogura; Jean-Marc Latour; Britt Hedman; Keith O Hodgson; Wonwoo Nam; Edward I Solomon
Journal: J Am Chem Soc Date: 2012-07-06 Impact factor: 15.419

5. What factors influence the reactivity of C-H hydroxylation and C=C epoxidation by [Fe(IV)(L(ax))(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)](n+).

Authors: Wang Yi; Liu Yuan; Yang Kun; He Zhengwen; Tian Jing; Fei Xu; Guo Hong; Wang Yong
Journal: J Biol Inorg Chem Date: 2015-09-07 Impact factor: 3.358

An inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+.

1. Geometric and electronic structure/function correlations in non-heme iron enzymes.

Review 2. Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.

Review 3. Reaction mechanisms of mononuclear non-heme iron oxygenases.

Review 4. High-valent nonheme iron-oxo species in biomimetic oxidations.

Review 5. The road to non-heme oxoferryls and beyond.

6. Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center.

7. Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins.

8. Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex.

9. Synthesis, structure determination, and spectroscopic/computational characterization of a series of Fe(II)-thiolate model complexes: implications for Fe-S bonding in superoxide reductases.

10. Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex.

1. Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.

2. Steric hindrance effect of the equatorial ligand on Fe(IV)O and Ru(IV)O complexes: a density functional study.

3. Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.

4. [Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.

5. What factors influence the reactivity of C-H hydroxylation and C=C epoxidation by [Fe(IV)(L(ax))(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)](n+).

6. An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.

7. Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.

Review 8. O-O Bond Formation and Liberation of Dioxygen Mediated by N₅ -Coordinate Non-Heme Iron(IV) Complexes.

Review 2. Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.

Review 3. Reaction mechanisms of mononuclear non-heme iron oxygenases.

Review 4. High-valent nonheme iron-oxo species in biomimetic oxidations.

Review 5. The road to non-heme oxoferryls and beyond.

Review 8. O-O Bond Formation and Liberation of Dioxygen Mediated by N5 -Coordinate Non-Heme Iron(IV) Complexes.

Review 8. O-O Bond Formation and Liberation of Dioxygen Mediated by N₅ -Coordinate Non-Heme Iron(IV) Complexes.