Literature DB >> 18729364

Eta2-organoazide complexes of nickel and their conversion to terminal imido complexes via dinitrogen extrusion.

Rory Waterman1, Gregory L Hillhouse.   

Abstract

1-Adamantyl- and mesitylazide react with [(dtbpe)Ni]2(eta2-mu-C6H6) to give the eta2 organic azide adducts (dtbpe)Ni(eta2-N3R) (R = Ad, 3a; Mes, 3b) that have been isolated in good yields and crystallographically characterized. These azide adducts are intermediates in the formation of the corresponding terminal imido complexes (dtbpe)NiNR (R = Ad, 4a; Mes, 4b), undergoing intramolecular loss of dinitrogen upon mild thermolysis.

Entities:  

Year:  2008        PMID： 18729364     DOI： 10.1021/ja805530z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Intramolecular Fe(II)-catalyzed N-O or N-N bond formation from aryl azides.

Authors:  Benjamin J Stokes; Carl V Vogel; Linda K Urnezis; Minjie Pan; Tom G Driver
Journal:  Org Lett       Date:  2010-06-18       Impact factor: 6.005

2.  Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry.

Authors:  Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2016-02-04       Impact factor: 15.419

3.  Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C-H Amination Efficacy.

Authors:  Yunjung Baek; Elisabeth T Hennessy; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2019-10-10       Impact factor: 15.419

4.  Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactions.

Authors:  David E Herbert; Nadia C Lara; Theodor Agapie
Journal:  Chemistry       Date:  2013-10-14       Impact factor: 5.236

5.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

6.  Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Authors:  Vlad M Iluc; Alexander J M Miller; John S Anderson; Marisa J Monreal; Mark P Mehn; Gregory L Hillhouse
Journal:  J Am Chem Soc       Date:  2011-07-28       Impact factor: 15.419

7.  Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azides.

Authors:  Benjamin J Stokes; Sheng Liu; Tom G Driver
Journal:  J Am Chem Soc       Date:  2011-03-14       Impact factor: 15.419

8.  Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source.

Authors:  Quyen Nguyen; Ke Sun; Tom G Driver
Journal:  J Am Chem Soc       Date:  2012-04-24       Impact factor: 15.419

9.  Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.

Authors:  Subrata Kundu; Enrico Miceli; Erik Farquhar; Florian Felix Pfaff; Uwe Kuhlmann; Peter Hildebrandt; Beatrice Braun; Claudio Greco; Kallol Ray
Journal:  J Am Chem Soc       Date:  2012-08-31       Impact factor: 15.419

10.  Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.

Authors:  Quyen Nguyen; Tuyen Nguyen; Tom G Driver
Journal:  J Am Chem Soc       Date:  2013-01-03       Impact factor: 15.419
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