Literature DB >> 23265139

Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.

Quyen Nguyen1, Tuyen Nguyen, Tom G Driver.   

Abstract

Iron(II) bromide catalyzes the transformation of ortho-substituted aryl azides into 2,3-disubstituted indoles through a tandem ethereal C-H bond amination [1,2]-shift reaction. The preference for the 1,2-shift component of the tandem reaction was established to be Me < 1° < 2° < Ph.

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Year:  2013        PMID： 23265139      PMCID： PMC3622273          DOI： 10.1021/ja3113565

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  67 in total

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5.  A diruthenium catalyst for selective, intramolecular allylic C-H amination: reaction development and mechanistic insight gained through experiment and theory.

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10.  Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenase.

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