Literature DB >> 18656907

Identification of very-long-chain polyunsaturated fatty acids from Amphidinium carterae by atmospheric pressure chemical ionization liquid chromatography-mass spectroscopy.

Tomás Rezanka1, Linda Nedbalová, Karel Sigler.   

Abstract

A method is described for the enrichment of very-long-chain polyunsaturated fatty acids (VLCPUFAs) from total fatty acids of Amphidinium carterae and their identification as picolinyl esters by means of microbore liquid chromatography-mass spectrometry with atmospheric pressure chemical ionization (LC-MS/APCI). The combination of argentation TLC and LC-MS/APCI was used to identify unusual VLCPUFAs up to hexatriacontaoctaenoic acid. Two acids, 36:7n-6 and 36:8n-3, were also synthesized to unambiguously confirm their structure. The possibilities of VLCPUFAs biosynthesis are proposed.

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Year:  2008        PMID: 18656907     DOI: 10.1016/j.phytochem.2008.06.011

Source DB:  PubMed          Journal:  Phytochemistry        ISSN: 0031-9422            Impact factor:   4.072


  3 in total

Review 1.  Retinal very long-chain PUFAs: new insights from studies on ELOVL4 protein.

Authors:  Martin-Paul Agbaga; Md Nawajes A Mandal; Robert E Anderson
Journal:  J Lipid Res       Date:  2010-03-18       Impact factor: 5.922

2.  Occurrence of Hexacosapolyenoic Acids 26:7(n-3), 26:6(n-3), 26:6(n-6) and 26:5(n-3) in Deep-Sea Brittle Stars from Near the Kuril Islands.

Authors:  Vasily Svetashev; Vladimir Kharlamenko
Journal:  Lipids       Date:  2015-06-03       Impact factor: 1.880

3.  Efficient synthesis of the very-long-chain n-3 fatty acids, tetracosahexaenoic acid (C24:6n-3) and tricosahexaenoic acid (C23:6n-3).

Authors:  Toshimasa Itoh; Ayako Tomiyasu; Keiko Yamamoto
Journal:  Lipids       Date:  2011-02-24       Impact factor: 1.880

  3 in total

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