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Literature DB >> 18655208

Hydrogen and amine activation by a frustrated Lewis pair of a bulky N-heterocyclic carbene and B(C6F5)3.

Preston A Chase¹, Douglas W Stephan.

Abstract

Entities: Chemical Disease

Year: 2008 PMID： 18655208 DOI： 10.1002/anie.200802596

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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18 in total

1. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

Authors: Jennifer Möricke; Birgit Wibbeling; Constantin G Daniliuc; Gerald Kehr; Gerhard Erker
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

2. Stable singlet carbenes as mimics for transition metal centers.

Authors: David Martin; Michele Soleilhavoup; Guy Bertrand
Journal: Chem Sci Date: 2011-01-01 Impact factor: 9.825

3. A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes.

Authors: Konstantin Chernichenko; Adám Madarász; Imre Pápai; Martin Nieger; Markku Leskelä; Timo Repo
Journal: Nat Chem Date: 2013-07-07 Impact factor: 24.427

4. Superelectrophilic intermediates in nitrogen-directed aromatic borylation.

Authors: Timothy S De Vries; Aleksandrs Prokofjevs; Jeremy N Harvey; Edwin Vedejs
Journal: J Am Chem Soc Date: 2009-10-21 Impact factor: 15.419

5. Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.

Authors: Kang-sang Lee; Adil R Zhugralin; Amir H Hoveyda
Journal: J Am Chem Soc Date: 2009-06-03 Impact factor: 15.419

Hydrogen and amine activation by a frustrated Lewis pair of a bulky N-heterocyclic carbene and B(C6F5)3.

1. Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

2. Stable singlet carbenes as mimics for transition metal centers.

3. A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes.

4. Superelectrophilic intermediates in nitrogen-directed aromatic borylation.

5. Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.

6. Main-group elements as transition metals.

7. Metal-free hydrogenation catalyzed by an air-stable borane: use of solvent as a frustrated Lewis base.

8. A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes.

9. Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH₂SiMe₃)₃-Induced C-H Functionalizations.

10. Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.