| Literature DB >> 18506228 |
Alan M Kenwright1, Ilya Kuprov, Elena De Luca, David Parker, Shashi U Pandya, P Kanthi Senanayake, David G Smith.
Abstract
Experimental measurements and theoretical analysis of magnetic properties, structural dynamics and acid-base equilibria for several lanthanide(III) complexes with tetraazacyclododecane derivatives as 19F NMR chemical shift pH probes are presented; pKa values vary between 6.9 and 7.7, with 18 to 40 ppm chemical shift differences between the acidic and basic forms for Ho(III) complexes possessing T1 values of 10 to 30 ms (4.7-9.4 T, 295 K).Entities:
Mesh：
Substances：
Year: 2008 PMID： 18506228 DOI： 10.1039/b802838a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222