Literature DB >> 18498194

The structure of polymer-supported triphenylphosphine ditriflate: a potentially useful reagent in organic synthesis.

Maria J Petersson1, Ian D Jenkins, Wendy A Loughlin.   

Abstract

The structure of a polymer-supported version of the Hendrickson "POP" reagent, prepared by the reaction of polymer-supported triphenylphosphine oxide 1 with triflic anhydride, is established as an equilibrium mixture of polymer-supported triphenylphosphine ditriflate 3 (delta 79.4 ppm) and polymer-supported phosphonium anhydride 4 (delta 73.3 ppm). The (31)P NMR chemical shift reported previously for 3 is shown to be incorrect.

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Year:  2008        PMID: 18498194     DOI: 10.1021/jo800447v

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  3 in total

1.  Preparation of (-)-Nutlin-3 using enantioselective organocatalysis at decagram scale.

Authors:  Tyler A Davis; Anna E Vilgelm; Ann Richmond; Jeffrey N Johnston
Journal:  J Org Chem       Date:  2013-10-15       Impact factor: 4.354

2.  A simple and rapid protocol for the synthesis of phenacyl derivatives using macroporous polymer-supported reagents.

Authors:  Ali R Kiasat; Soheil Sayyahi
Journal:  Mol Divers       Date:  2009-09-11       Impact factor: 2.943

3.  Catalytic, Enantioselective Synthesis of Stilbene cis-Diamines: A Concise Preparation of (-)-Nutlin-3, a Potent p53/MDM2 Inhibitor.

Authors:  Tyler A Davis; Jeffrey N Johnston
Journal:  Chem Sci       Date:  2011-03-25       Impact factor: 9.825

  3 in total

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