Literature DB >> 18335937

Unusually weak metal-hydrogen bonds in HV(CO)4(P-P) and their effectiveness as H(*) donors.

Jongwook Choi1, Mary E Pulling, Deborah M Smith, Jack R Norton.   

Abstract

The V-H bonds in HV(CO)4(P-P) are unusually weak (55 to 58 kcal/mol). They transfer H* to styrene more rapidly than CpCr(CO)3H does and are effective stoichiometric reagents for the cyclization of appropriate 1,6-dienes.

Entities:  

Year:  2008        PMID： 18335937     DOI： 10.1021/ja710455c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  17 in total

1.  Hydride-containing models for the active site of the nickel-iron hydrogenases.

Authors:  Bryan E Barton; Thomas B Rauchfuss
Journal:  J Am Chem Soc       Date:  2010-10-27       Impact factor: 15.419

Review 2.  Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors:  David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal:  Chem Rev       Date:  2016-06-29       Impact factor: 60.622

3.  The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer.

Authors:  Samantha A Green; Steven W M Crossley; Jeishla L M Matos; Suhelen Vásquez-Céspedes; Sophia L Shevick; Ryan A Shenvi
Journal:  Acc Chem Res       Date:  2018-11-08       Impact factor: 22.384

4.  H· Transfer-Initiated Synthesis of γ-Lactams: Interpretation of Cycloisomerization and Hydrogenation Ratios.

Authors:  Chris Lorenc; Hunter B Vibbert; Chengbo Yao; Jack R Norton; Michael Rauch
Journal:  ACS Catal       Date:  2019-10-09       Impact factor: 13.084

5.  Synthetic Applications of Proton-Coupled Electron Transfer.

Authors:  Emily C Gentry; Robert R Knowles
Journal:  Acc Chem Res       Date:  2016-07-29       Impact factor: 22.384

6.  Catalyzing the Hydrodefluorination of CF3-Substituted Alkenes by PhSiH3. H• Transfer from a Nickel Hydride.

Authors:  Chengbo Yao; Shuai Wang; Jack Norton; Matthew Hammond
Journal:  J Am Chem Soc       Date:  2020-01-24       Impact factor: 15.419

Review 7.  Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.

Authors:  David C Miller; Kyle T Tarantino; Robert R Knowles
Journal:  Top Curr Chem (Cham)       Date:  2016-05-09

8.  Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers.

Authors:  Christopher R Waidmann; Xin Zhou; Erin A Tsai; Werner Kaminsky; David A Hrovat; Weston Thatcher Borden; James M Mayer
Journal:  J Am Chem Soc       Date:  2009-04-08       Impact factor: 15.419

9.  Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

Authors:  Steven W M Crossley; Carla Obradors; Ruben M Martinez; Ryan A Shenvi
Journal:  Chem Rev       Date:  2016-07-27       Impact factor: 60.622

10.  Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes.

Authors:  Renyuan Pony Yu; Jonathan M Darmon; Carsten Milsmann; Grant W Margulieux; S Chantal E Stieber; Serena DeBeer; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2013-08-22       Impact factor: 15.419
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