| Literature DB >> 18331056 |
Ronald J Rahaim1, Jared T Shaw.
Abstract
A rapid and high-yielding silylation of terminal alkynes employing TMSOTf and catalytic quantities of Zn(OTf)2 has been developed. The reaction works well for a variety of substrates including reactive esters. Fifteen examples with yields of >90% are reported.Entities:
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Year: 2008 PMID： 18331056 DOI： 10.1021/jo702557d
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354