Literature DB >> 18301864

Simulation of charge reversal in salty environments: giant overcharging?

O Lenz1, C Holm.   

Abstract

We have performed MD simulations of a highly charged colloid in a solution of 3:1 and additional 1:1 salt. The dependency of the colloid's inverted charge on the concentration of the additional 1:1 salt has been studied. Most theories predict, that the inverted charge increases when the concentration of monovalent salt grows, up to what is called giant overcharging, while experiments and simulational studies observe the opposite. Our simulations agree with the experimental findings and shed light onto the weaknesses of the theories.

Entities:  

Year:  2008        PMID: 18301864     DOI: 10.1140/epje/i2007-10260-x

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  10 in total

1.  Screening of a macroion by multivalent ions: correlation-induced inversion of charge.

Authors:  B I Shklovskii
Journal:  Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics       Date:  1999-11

2.  Macroions in salty water with multivalent ions: giant inversion of charge

Authors: 
Journal:  Phys Rev Lett       Date:  2000-08-14       Impact factor: 9.161

Review 3.  Overcharging in colloids: beyond the Poisson-Boltzmann approach.

Authors:  Manuel Quesada-Pérez; Enrique González-Tovar; Alberto Martín-Molina; Marcelo Lozada-Cassou; Roque Hidalgo-Alvarez
Journal:  Chemphyschem       Date:  2003-03-17       Impact factor: 3.102

4.  Effects of asymmetric salt and a cylindrical macroion on charge inversion: electrophoresis by molecular dynamics simulations.

Authors:  Motohiko Tanaka
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2003-12-11

5.  Direct observation of charge inversion by multivalent ions as a universal electrostatic phenomenon.

Authors:  K Besteman; M A G Zevenbergen; H A Heering; S G Lemay
Journal:  Phys Rev Lett       Date:  2004-10-20       Impact factor: 9.161

6.  Simulation of electric double layers undergoing charge inversion: mixtures of mono- and multivalent ions.

Authors:  M Quesada-Pérez; A Martín-Molina; R Hidalgo-Alvarez
Journal:  Langmuir       Date:  2005-09-27       Impact factor: 3.882

7.  Smoluchowski equation and the colloidal charge reversal.

Authors:  Alexandre Diehl; Yan Levin
Journal:  J Chem Phys       Date:  2006-08-07       Impact factor: 3.488

8.  Testing one component plasma models on colloidal overcharging phenomena.

Authors:  Alberto Martín-Molina; José Alberto Maroto-Centeno; Roque Hidalgo-Alvarez; Manuel Quesada-Pérez
Journal:  J Chem Phys       Date:  2006-10-14       Impact factor: 3.488

9.  Charge inversion by multivalent ions: dependence on dielectric constant and surface-charge density.

Authors:  K Besteman; M A G Zevenbergen; S G Lemay
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2005-12-01

10.  Electrophoresis of a charge-inverted macroion complex: Molecular-dynamics study.

Authors:  Motohiko Tanaka; A Yu Grosberg
Journal:  Eur Phys J E Soft Matter       Date:  2002-04       Impact factor: 1.890

  10 in total
  1 in total

Review 1.  Multivalent ions and biomolecules: Attempting a comprehensive perspective.

Authors:  Olga Matsarskaia; Felix Roosen-Runge; Frank Schreiber
Journal:  Chemphyschem       Date:  2020-07-20       Impact factor: 3.102

  1 in total

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