A topography/chemical composition gradient polystyrene surface: toward the investigation of the relationship between surface wettability and surface structure and chemical composition.

In this paper, we have prepared of a topography/chemical composition gradient polystyrene (PS) surface, i.e., an orthogonal gradient surface, to investigate the relationship between surface wettability and surface structure and chemical composition. The prepared surface shows a one-dimensional gradient in wettability in the x, y, and diagonal directions, including hydrophobic to hydrophilic, superhydrophobic to hydrophobic, superhydrophobic to superhydrophilic gradients, and so forth. These one-dimensional gradients have different gradient values, gradient range, and contact angle hysteresis, which lie on both the surface roughness and the surface compositions. From the trend of variation of contact angle hysteresis, it can be concluded that the transition from the Cassie's model to the Wenzel's model occurs both by decreasing surface roughness and by increasing surface hydrophilic compositions. Moreover, the transition is more effective via changing surface chemical composition than changing surface roughness herein.