| Literature DB >> 18097486 |
Ian R Crossley1, Anthony F Hill.
Abstract
The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt)3}]Cl(Pt-->B)8 (mt = methimazolyl, Tol = C6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{kappa 2-S,S'-HB(mt)3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt-->B)8.Entities:
Year: 2007 PMID： 18097486 DOI： 10.1039/b712058c
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390