Literature DB >> 18052284

Alkane hydroxylation by a nonheme iron catalyst that challenges the heme paradigm for oxygenase action.

Anna Company1, Laura Gómez, Mireia Güell, Xavi Ribas, Josep M Luis, Lawrence Que, Miquel Costas.   

Abstract

A nonheme iron catalyst catalyzed stereoselective oxidation of alkanes with H2O2 with remarkable efficiency and exhibiting an unprecedented high incorporation of water into the oxidized products. The present results challenge the canonical description of oxygenases, the standard oxo-hydroxo tautomerism that applies to heme systems and serves as a precedent for alternative pathways for the oxidation of hydrocarbons at nonheme iron oxygenases.

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Year:  2007        PMID： 18052284     DOI： 10.1021/ja077761n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

1.  Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions.

Authors:  Irene Prat; Jennifer S Mathieson; Mireia Güell; Xavi Ribas; Josep M Luis; Leroy Cronin; Miquel Costas
Journal:  Nat Chem       Date:  2011-09-04       Impact factor: 24.427

2.  One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.

Authors:  Katherine M Van Heuvelen; Adam T Fiedler; Xiaopeng Shan; Raymond F De Hont; Katlyn K Meier; Emile L Bominaar; Eckard Münck; Lawrence Que
Journal:  Proc Natl Acad Sci U S A       Date:  2012-07-11       Impact factor: 11.205

3.  Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.

Authors:  Anna Company; Irene Prat; Jonathan R Frisch; Ruben Mas-Ballesté; Mireia Güell; Gergely Juhász; Xavi Ribas; Eckard Münck; Josep M Luis; Lawrence Que; Miquel Costas
Journal:  Chemistry       Date:  2011-01-05       Impact factor: 5.236

4.  Equilibrating (L)FeIII-OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH.

Authors:  Williamson N Oloo; Rahul Banerjee; John D Lipscomb; Lawrence Que
Journal:  J Am Chem Soc       Date:  2017-11-27       Impact factor: 15.419

5.  Efficient water oxidation catalysts based on readily available iron coordination complexes.

Authors:  Julio Lloret Fillol; Zoel Codolà; Isaac Garcia-Bosch; Laura Gómez; Juan José Pla; Miquel Costas
Journal:  Nat Chem       Date:  2011-09-04       Impact factor: 24.427

Review 6.  Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

Authors:  Giorgio Olivo; Olaf Cussó; Margarida Borrell; Miquel Costas
Journal:  J Biol Inorg Chem       Date:  2017-01-25       Impact factor: 3.358

7.  High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic FeIV=O Complexes.

Authors:  Lawrence Que
Journal:  Bull Jpn Soc Coord Chem       Date:  2013-11

8.  Shape-selective interception by hydrocarbons of the O2-derived oxidant of a biomimetic nonheme iron complex.

Authors:  Anusree Mukherjee; Marlène Martinho; Emile L Bominaar; Eckard Münck; Lawrence Que
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

9.  Strain release in C-H bond activation?

Authors:  Ke Chen; Albert Eschenmoser; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

10.  Resolving Oxygenation Pathways in Manganese-Catalyzed C(sp3)-H Functionalization via Radical and Cationic Intermediates.

Authors:  Marco Galeotti; Laia Vicens; Michela Salamone; Miquel Costas; Massimo Bietti
Journal:  J Am Chem Soc       Date:  2022-04-13       Impact factor: 16.383
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