Literature DB >> 18052157

Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.

Ariela W Kaspi1, Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok.   

Abstract

Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.

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Year:  2007        PMID： 18052157     DOI： 10.1021/ic701722f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  21 in total

1.  Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.

Authors:  Nicholas D Ball; J Brannon Gary; Yingda Ye; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2011-04-22       Impact factor: 15.419

2.  Pd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes.

Authors:  Xisheng Wang; Dasheng Leow; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2011-08-16       Impact factor: 15.419

3.  Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactor.

Authors:  Timothy Noël; Thomas J Maimone; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2011-08-11       Impact factor: 15.336

4.  Heterocycle Formation via Palladium-Catalyzed C-H Functionalization.

Authors:  Tian-Sheng Mei; Lei Kou; Sandy Ma; Keary M Engle; Jin-Quan Yu
Journal:  Synthesis (Stuttg)       Date:  2012-05-25       Impact factor: 3.157

5.  Deoxyfluorination of phenols.

Authors:  Pingping Tang; Weike Wang; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2011-07-12       Impact factor: 15.419

Review 6.  Catalysis for fluorination and trifluoromethylation.

Authors:  Takeru Furuya; Adam S Kamlet; Tobias Ritter
Journal:  Nature       Date:  2011-05-26       Impact factor: 49.962

7.  Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible.

Authors:  Shu-Bin Zhao; Jennifer J Becker; Michel R Gagné
Journal:  Organometallics       Date:  2011-08-08       Impact factor: 3.876

8.  Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands.

Authors:  Nicholas D Ball; Jeff W Kampf; Melanie S Sanford
Journal:  Dalton Trans       Date:  2009-11-26       Impact factor: 4.390

Review 9.  Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.

Authors:  Keary M Engle; Tian-Sheng Mei; Xisheng Wang; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-24       Impact factor: 15.336

10.  Catalytic enantioselective cyclization and C3-fluorination of polyenes.

Authors:  Nikki A Cochrane; Ha Nguyen; Michel R Gagne
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419
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