Literature DB >> 17989819

Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source.

Jeremiah D Harden1, Joshua V Ruppel, Guang-Yao Gao, X Peter Zhang.   

Abstract

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp(3) C-H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

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Year:  2007        PMID： 17989819     DOI： 10.1039/b710677g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

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8.  C-H Amination Mediated by Cobalt Organoazide Adducts and the Corresponding Cobalt Nitrenoid Intermediates.

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