Literature DB >> 17957282

On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase.

Stephen P Best1, Stacey J Borg, Jonathan M White, Mathieu Razavet, Christopher J Pickett.   

Abstract

We show that a dinuclear assembly apparently providing the first example of a synthetic molecule exhibiting key features of the diiron subsite of [FeFe] hydrogenase, viz. CO-bridging of a coordinatively unsaturated, dithiolate-bridged mixed-valence diiron centre, is in fact a diamagnetic tetranuclear complex.

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Year:  2007        PMID： 17957282     DOI： 10.1039/b712758h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Diiron dithiolato carbonyls related to the H(ox)CO state of [FeFe]-hydrogenase.

Authors:  Aaron K Justice; Mark J Nilges; Thomas B Rauchfuss; Scott R Wilson; Luca De Gioia; Giuseppe Zampella
Journal:  J Am Chem Soc       Date:  2008-03-15       Impact factor: 15.419

Review 2.  Small molecule mimics of hydrogenases: hydrides and redox.

Authors:  Frédéric Gloaguen; Thomas B Rauchfuss
Journal:  Chem Soc Rev       Date:  2008-10-31       Impact factor: 54.564

3.  Catalyst accessibility to chemical reductants in metal-organic frameworks.

Authors:  Souvik Roy; Vlad Pascanu; Sonja Pullen; Greco González Miera; Belén Martín-Matute; Sascha Ott
Journal:  Chem Commun (Camb)       Date:  2017-03-06       Impact factor: 6.222

4.  Lewis acid protection turns cyanide containing [FeFe]-hydrogenase mimics into proton reduction catalysts.

Authors:  Holly J Redman; Ping Huang; Michael Haumann; Mun Hon Cheah; Gustav Berggren
Journal:  Dalton Trans       Date:  2022-03-22       Impact factor: 4.390

5.  Electronic characterization of redox (non)-innocent Fe2S2 reference systems: a multi K-edge X-ray spectroscopic study.

Authors:  J P H Oudsen; B Venderbosch; T J Korstanje; M Tromp
Journal:  RSC Adv       Date:  2020-01-02       Impact factor: 4.036

6.  [FeFe] hydrogenase: protonation of {2Fe3S} systems and formation of super-reduced hydride states.

Authors:  Aušra Jablonskytė; Joseph A Wright; Shirley A Fairhurst; Lee R Webster; Christopher J Pickett
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-30       Impact factor: 15.336

7.  Hepta-carbonyl-bis-(μ-propane-1,3-di-thiol-ato)triiron(I,II)(2 Fe-Fe).

Authors:  Mingqiang Hu; Chengbing Ma; Huimin Wen; Honghua Cui; Changneng Chen
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-03-08
  7 in total

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