Higher-order virial coefficients of water models.

We use the Mayer sampling method, with both direct and overlap sampling, to calculate and compare classical virial coefficients up to B6 for various water models (SPC, SPC/E, MSPC/E, TIP3P, and TIP4P). The precision of the computed values ranges from 0.1% for B2 to an average of 25% for B6. When expressed in a form scaled by the critical properties, the values of the coefficients for SPC water are observed to greatly exceed the magnitude of corresponding coefficients for the simple Lennard-Jones model. We examine the coefficients in the context of the equation of state and the Joule-Thomson coefficient. Comparisons of these properties are made both to established molecular simulation data for each respective model and to real water. For all models, the virial series up to B5 describes the equation of state along the saturated vapor line better than the series that includes B6. At supercritical temperatures, however, the sixth-order series often describes pressure-volume-temperature behavior better than the fifth-order series. For example, the sixth-order virial equation of state for SPC/E water predicts the 673 K isotherm within 8% of published molecular simulation values up to a density of 9 mol/L (roughly half the critical density of SPC/E water).