Literature DB >> 17844761

Insertion of arynes into carbon-halogen sigma-bonds: regioselective acylation of aromatic rings.

Hiroto Yoshida1, Yasuhiro Mimura, Joji Ohshita, Atsutaka Kunai.   

Abstract

Arynes were found to insert into carbon-halogen sigma-bonds of various acid halides, enabling acyl and halogen moieties to be introduced simultaneously into adjacent positions of aromatic rings.

Entities:  

Year:  2007        PMID： 17844761     DOI： 10.1039/b701581j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Intermolecular C-O addition of carboxylic acids to arynes.

Authors:  Anton V Dubrovskiy; Richard C Larock
Journal:  Org Lett       Date:  2010-07-16       Impact factor: 6.005

2.  Insertion of arynes into N-halo bonds: a direct approach to o-haloaminoarenes.

Authors:  Charles E Hendrick; Stacey L McDonald; Qiu Wang
Journal:  Org Lett       Date:  2013-06-24       Impact factor: 6.005

3.  Synthesis of 9-Substituted Xanthenes by the Condensation of Arynes with ortho-Hydroxychalcones.

Authors:  Chun Lu; Anton V Dubrovskiy; Richard C Larock
Journal:  Tetrahedron Lett       Date:  2012-02-25       Impact factor: 2.415

4.  Intermolecular C-O Addition of Carboxylic Acids to Arynes: Synthesis of o-Hydroxyaryl Ketones, Xanthones, 4-Chromanones, and Flavones.

Authors:  Anton V Dubrovskiy; Richard C Larock
Journal:  Tetrahedron       Date:  2013-02-04       Impact factor: 2.457

5.  Benzyne click chemistry: synthesis of benzotriazoles from benzynes and azides.

Authors:  Feng Shi; Jesse P Waldo; Yu Chen; Richard C Larock
Journal:  Org Lett       Date:  2008-05-14       Impact factor: 6.005
  5 in total

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